Optimization of salicylic acid removal by electro Fenton process in a continuous stirred tank reactor using response surface methodology

被引：17

作者：

George, Stephy Jacqueline ^{[1
]}

Gandhimathi, Rajan ^{[1
]}

Nidheesh, Puthiya Veetil ^{[1
]}

Ramesh, Sreekrishnaperumal Thanga ^{[1
]}

机构：

[1] Natl Inst Technol, Dept Civil Engn, Tiruchirappalli, Tamil Nadu, India

来源：

DESALINATION AND WATER TREATMENT | 2016年 / 57卷 / 09期

关键词：

Optimization; Response surface methodology; Electro Fenton; Salicylic acid; ADVANCED OXIDATION PROCESSES; AQUEOUS-SOLUTION; HYDROGEN-PEROXIDE; RHODAMINE-B; DEGRADATION; WATER; DYES;

D O I：

10.1080/19443994.2014.992970

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aim of this work is to apply the response surface methodology (RSM) to optimize several operating conditions that significantly affect the removal of salicylic acid (SA) from aqueous solution by electro Fenton (EF) process. Optimization of the EF process for the removal of 100mg/L of SA solution was carried out using a face centred central composite design in RSM to investigate the joint influence of four variables (catalyst concentration, pH, voltage and electrolysis time) at three different levels. 70.45% of SA was removed at the optimum catalyst concentration of 5.10mg/L, pH of 2.42, voltage of 2.70V and electrolysis time of 6h. A validation experiment was performed under the operating conditions predicted by the models.

引用

页码：4234 / 4244

页数：11

共 34 条

[1] Comparison of three advanced oxidation processes for degradation of textile dyes [J].

Aplin, R ;

Waite, TD .

WATER SCIENCE AND TECHNOLOGY, 2000, 42 (5-6) :345-354

[2] Hydrogen peroxide lifetime as an indicator of the efficiency of 3-chlorophenol Fenton's and Fenton-like oxidation in soils [J].

Baciocchi, R ;

Boni, MR ;

D'Aprile, L .

JOURNAL OF HAZARDOUS MATERIALS, 2003, 96 (2-3) :305-329

[3] Fenton-biological treatment processes for the removal of some pharmaceuticals from industrial wastewater [J].

Badawy, Mohamed I. ;

Wahaab, Rifaat A. ;

El-Kalliny, A. S. .

JOURNAL OF HAZARDOUS MATERIALS, 2009, 167 (1-3) :567-574

[4] Oxidation of pesticides by in situ electrogenerated hydrogen peroxide: Study for the degradation of 2,4-dichlorophenoxyacetic acid [J].

Badellino, Carla ;

Rodrigues, Christiane Arruda ;

Bertazzoli, Rodnei .

JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (02) :856-864

[5] Optimizing properties of nanoclay-nitrile rubber (NBR) composites using Face Centred Central Composite Design [J].

Balachandran, Meera ;

Devanathan, Sriram ;

Muraleekrishnan, R. ;

Bhagawan, S. S. .

MATERIALS & DESIGN, 2012, 35 :854-862

[6] BLOOD LACTATE AND KETONE-BODY CONCENTRATIONS IN SALICYLATE INTOXICATION [J].

BARTELS, PD ;

LUNDJACOBSEN, H .

HUMAN TOXICOLOGY, 1986, 5 (06) :363-366

[7] Electrochemical degradation of bromopyrogallol red in presence of cobalt ions [J].

Chen, JS ;

Liu, MC ;

Zhang, JD ;

Xian, YZ ;

Jin, LT .

CHEMOSPHERE, 2003, 53 (09) :1131-1136

[8] Electrochemical removal of salicylic acid from aqueous solutions using aluminum electrodes [J].

Chou, Wei-Lung ;

Wang, Chih-Ta ;

Huang, Kai-Yu ;

Liu, Te-Chao .

DESALINATION, 2011, 271 (1-3) :55-61

[9] Oxidation of Levafix CA reactive azo-dyes in industrial wastewater of textile dyeing by electro-generated Fenton's reagent [J].

El-Desoky, Hanaa S. ;

Ghoneim, Mohamed M. ;

El-Sheikh, Ragaa ;

Zidan, Naglaa M. .

JOURNAL OF HAZARDOUS MATERIALS, 2010, 175 (1-3) :858-865

[10] Ecotoxicological impact of pharmaceuticals found in treated wastewaters:: study of carbamazepine, clofibric acid, and diclofenac [J].

Ferrari, B ;

Paxéus, N ;

Lo Giudice, R ;

Pollio, A ;

Garric, J .

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2003, 55 (03) :359-370

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