Degraded limonoids from Melia azedarach and biogenetic implications

被引：40

作者：

D'Ambrosio, M ^{[1
]}

Guerriero, A ^{[1
]}

机构：

[1] Univ Trent, Chim Bioorgan Lab, I-38050 Povo, Italy

来源：

PHYTOCHEMISTRY | 2002年 / 60卷 / 04期

关键词：

Melia azedarach; Meliaceae; chinaberry; degraded limonoids; teracrylmelazolide A; teracrylmelazolide B; melazolide A; pyroangolensolide; 30-hydroxyfraxinellone; 9; alpha-; and; beta-hydroxyfraxinellone;

D O I：

10.1016/S0031-9422(02)00107-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The roots of Melia azedarach yielded three new degraded limonoids: teracrylmelazolide A, melazolide A and teracrylmelazolide B, possessing a previously undescribed skeleton. The known pyroangolensolide, fraxinellone and its three derivatives, 30-hydroxyfraxinellone, 9alpha- and 9beta-hydroxyfraxinellone, were also isolated. Their stereochemisty was elucidated on the basis of spectral data and chemical reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：419 / 424

页数：6

共 9 条

[1]

AKHYLA A, 1999, FORTSCHR CHEM ORGAN, V78, P47

[2]

[Anonymous], STEREOCHEMISTRY FUND

[3] A DEGRADED LIMONOID FROM FAGAROPSIS-GLABRA [J].