Graphene oxide reduction during surface-initiated atom transfer radical polymerization of glycidyl methacrylate: Controlling electro-responsive properties

被引：38
作者：
Mrlik, Miroslav [1 ]
Ilcikova, Marketa [2 ]
Plachy, Tomas [1 ]
Pavlinek, Vladimir [1 ]
Spitalsky, Zdenko [2 ]
Mosnacek, Jaroslav [2 ]
机构：
[1] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Zlin 76001, Czech Republic
[2] Slovak Acad Sci, Inst Polymer, Bratislava 84541, Slovakia
来源：
CHEMICAL ENGINEERING JOURNAL | 2016年 / 283卷
关键词：
Graphene oxide; Poly(glycidyl methacrylate); ATRP; Surface initiated polymerization; Electrorheology; ANILINE OLIGOMERS; GRAPHITE OXIDE; ELECTRORHEOLOGY; PARTICLES; SHEETS;
D O I：
10.1016/j.cej.2015.08.013
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Unique grafting of the poly(glycidyl methacrylate) from the surface of graphene oxide (GO) with the controllable reduction of GO particles was performed in a single-step reaction using atom transfer radical polymerization technique. The control of the GO surface reduction and modification can be achieved by appropriate selection of the ratio between tertiary amine and GO particle contents. Finely tuned electrical conductivity of the GO-PGMA particles enables simple tailoring of electro-responsive properties of their silicone oil suspensions. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：717 / 720
页数：4
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