Wettability of Thin Silicate-Containing Hydroxyapatite Films Formed by RF-Magnetron Sputtering

被引:6
作者
Gorodzha, S. N. [1 ]
Surmeneva, M. A. [1 ]
Surmenev, R. A. [1 ]
Gribennikov, M. V. [1 ]
Pichugin, V. F. [1 ]
Sharonova, A. A. [1 ]
Pustovalova, A. A. [1 ]
Prymack, O. [2 ]
Epple, M. [2 ]
Wittmar, A. [3 ]
Ulbricht, M. [3 ]
Gogolinskii, K. V. [4 ]
Kravchuk, K. S. [4 ]
机构
[1] Natl Res Tomsk Polytech Univ, Tomsk, Russia
[2] Univ Duisburg Essen, Inst Inorgan Chem, Essen, Germany
[3] Univ Duisburg Essen, Chair Tech Chem 2, Essen, Germany
[4] Tech Inst Superhard & Novel Carbon Mat, Troitsk, Russia
关键词
calcium-phosphate coating; RF-magnetron sputtering; biocompatibility; wetting ability; SURFACE; COATINGS; RELEASE; ENERGY;
D O I
10.1007/s11182-014-0157-2
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Using the methods of electron and atomic force microscopy, X-ray structural analysis and measurements of the wetting angle, the features of morphology, structure, contact angle and free surface energy of silicon-containing calcium-phosphate coatings formed on the substrates made from titanium VT1-0 and stainless steel 12Cr18Ni10Ti are investigated. It is shown that the coating - substrate system possesses bimodal roughness formed by the substrate microrelief and coating nanostructure, whose principal crystalline phase is represented by silicon-substituted hydroxiapatite with the size of the coherent scattering region (CSR) 18-26 nm. It is found out that the formation of a nanostructured coating on the surface of rough substrates makes them hydrophilic. The limiting angle of water wetting for the coatings formed on titanium and steel acquires the values in the following ranges: 90-92 and 101-104A degrees, respectively, and decreases with time.
引用
收藏
页码:1163 / 1169
页数:7
相关论文
共 25 条
  • [1] Boinovich LB, 2008, USP KHIM+, V77, P619
  • [2] Carlisle E.M., 1986, SILICON ESSENTIAL TR
  • [3] Chaikina MV, 2009, CHEM SUSTAIN DEV, V17, P507
  • [4] Dorozhkin SV, 2002, ANGEW CHEM, V114, P3260, DOI DOI 10.1002/1521-3757(20020902)114:17
  • [5] Response of MG63 osteoblast-like cells to titanium and titanium alloy is dependent on surface roughness and composition
    Lincks, J
    Boyan, BD
    Blanchard, CR
    Lohmann, CH
    Liu, Y
    Cochran, DL
    Dean, DD
    Schwartz, Z
    [J]. BIOMATERIALS, 1998, 19 (23) : 2219 - 2232
  • [6] Influence of strain on the surface wettability in crystalline HgCr2S4 thin films
    Mane, R. S.
    Todkar, V. V.
    Lokhande, C. D.
    Ahn, Ju-Hyun
    Han, Sung-Hwan
    [J]. NANOTECHNOLOGY, 2006, 17 (21) : 5393 - 5396
  • [7] Redey SA, 2000, J BIOMED MATER RES, V50, P353, DOI 10.1002/(SICI)1097-4636(20000605)50:3<353::AID-JBM9>3.0.CO
  • [8] 2-C
  • [9] Multifunctional ToF-SIMS: combinatorial mapping of gradient energy substrates
    Roberson, SV
    Fahey, AJ
    Sehgal, A
    Karim, A
    [J]. APPLIED SURFACE SCIENCE, 2002, 200 (1-4) : 150 - 164
  • [10] THERMODYNAMIC ASPECTS OF CELL SPREADING ON SOLID SUBSTRATA
    SCHAKENRAAD, JM
    BUSSCHER, HJ
    WILDEVUUR, CRH
    ARENDS, J
    [J]. CELL BIOPHYSICS, 1988, 13 (01): : 75 - 91