Ex Situ NMR Relaxometry of Metal-Organic Frameworks for Rapid Surface-Area Screening

被引：39

作者：

Chen, Joseph J. ^{[1
]}

Kong, Xueqian ^{[1
]}

Sumida, Kenji ^{[2
]}

Manumpil, Mary Anne ^{[2
]}

Long, Jeffrey R. ^{[2
]}

Reimer, Jeffrey A. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94703 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94703 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 46期

关键词：

high-throughput screening; metal-organic frameworks; microporous materials; NMR relaxometry; NMR spectroscopy; CARBON-DIOXIDE CAPTURE; HIGH-THROUGHPUT SYNTHESIS; PORE-SIZE DISTRIBUTIONS; SINGLE-SIDED NMR; POROUS-MEDIA; SUSCEPTIBILITY DIFFERENCES; COORDINATION POLYMER; HYDROGEN STORAGE; RELAXATION; DIFFUSION;

D O I：

10.1002/anie.201305247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Taking a relaxed approach: The NMR relaxation behavior of imbibed solvent has been used to estimate the surface area of a variety of microporous metal-organic frameworks and zeolites. This NMR technique is amenable to automation and can expedite the characterization of microporous materials by identifying any nonporous or low-surface-area structures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12043 / 12046

页数：4

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