Synthesis and property of silicone polymer from chrysotile asbestos by acid-leaching and silylation

被引：19

作者：

Habaue, Shigeki

Hirasa, Tetsuya

Akagi, Yuichi

Yamashita, Kiyotsugu

Kajiwara, Meisetsu ^{[1
]}

机构：

[1] Aichi Gakuin Univ, Sch Dent, Chikusa Ku, Nagoya, Aichi 4640034, Japan

[2] Yamagata Univ, Dept Chem & Chem Engn, Fac Engn, Yamagata 9928510, Japan

[3] Nozawa Corp, Fukaya, Saitama 3660812, Japan

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2006年 / 16卷 / 02期

关键词：

chrysotile asbestos; acid-leaching; silicone polymer; silylation reaction;

D O I：

10.1007/s10904-006-9038-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The porous, disordered, and fibrous silica derived from serpentine slag containing chrysotile asbestos by selective acid-leaching was converted to a silicone polymer through the silylation reaction of the silanol residue with chlorodimethylvinylsilane (DMVSCl). The polymer silylated with 1.2 equiv. of DMVSCl to the silica showed a 93% degree of silylation, which was fully soluble in various organic solvents. The Si-29-NMR measurement indicated that the obtained polymers have Q(4)-, Q(3), and M-type siloxane units.

引用

页码：155 / 160

页数：6