Processing surface sizing starch using oxidation, enzymatic hydrolysis and ultrasonic treatment methods-Preparation and application

被引:31
作者
Brenner, Tobias [1 ]
Kiessler, Birgit [1 ]
Radosta, Sylvia [2 ]
Arndt, Tiemo [1 ]
机构
[1] Papiertech Stiftung, D-01809 Heidenau, Germany
[2] Fraunhofer Inst Appl Polymer Res, D-14476 Potsdam, Germany
关键词
Starch degradation; Jet cooking; Ultrasonic; Molar mass; Surface sizing; Paper properties; INDUCED CAVITATION BUBBLES; HYDROGEN-BOND; JET-COOKING; VISCOSITY; DYNAMICS;
D O I
10.1016/j.carbpol.2015.10.086
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The surface application of starch is a well-established method for increasing paper strength. In surface sizing, a solution of degraded starch is applied to the paper. Two procedures have proved valuable for starch degradation in the paper mill: enzymatic and thermo-oxidative degradation. The objective of this study was to determine achievable efficiencies of cavitation in preparing degraded starch for surface application on paper. It was found that ultrasonic-assisted starch degradation can provide a starch solution that is suitable for surface sizing. The molecular composition of starch solutions prepared by ultrasonic treatment differed from that of starch solutions degraded by enzymes or by thermo-oxidation. Compared to commercial degradation processes, this resulted in intensified film formation and in greater penetration during surface sizing and ultimately in a higher starch content of the paper. Paper sized with ultrasonically treated starch solutions show the same strength properties compared to commercially sized paper. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:273 / 279
页数:7
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