Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6

被引：14

作者：

Han, Fei ^{[1
]}

Hu, Lei ^{[1
]}

Liu, Zhanning ^{[1
]}

Li, Qiang ^{[1
]}

Wang, Tao ^{[1
]}

Ren, Yang ^{[2
]}

Deng, Jinxia ^{[1
]}

Chen, Jun ^{[1
]}

Xing, Xianran ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China

[2] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA

来源：

INORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 02期

基金：

中国国家自然科学基金;

关键词：

CUBIC SCF3; ZERO; ZN; FE; CO; FERROMAGNETISM; DEPENDENCE; FLUORIDES; MN; NI;

D O I：

10.1039/c6qi00483k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 x 10(-6) K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix) ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

引用

页码：343 / 347

页数：5

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