Recent advances in non-noble metal electrocatalysts for nitrate reduction

被引：571

作者：

Zhang, Xi ^{[1
]}

Wang, Yuting ^{[1
]}

Liu, Cuibo ^{[1
]}

Yu, Yifu ^{[1
]}

Lu, Siyu ^{[3
]}

Zhang, Bin ^{[1
,2
]}

机构：

[1] Tianjin Univ, Inst Mol Plus, Sch Sci, Dept Chem, 92 Weijin Rd, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, 92 Weijin Rd, Tianjin 300072, Peoples R China

[3] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450000, Peoples R China

来源：

CHEMICAL ENGINEERING JOURNAL | 2021年 / 403卷

基金：

中国国家自然科学基金;

关键词：

Electrocatalysis; Non-noble metal materials; Nitrate reduction; Water treatment; DIE AUTOKATALYTISCHE NATUR; ZU SALPETRIGER SAURE; NANO TITANIUM ELECTRODE; BORON-DOPED DIAMOND; ELECTROCHEMICAL REDUCTION; COPPER ELECTRODES; ALLOY ELECTRODES; WASTE-WATER; HYDROGEN-PRODUCTION; REMOVING NITRATE;

D O I：

10.1016/j.cej.2020.126269

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Nitrate pollution has become a serious global problem, threatening human health and ecosystems. The electrochemical reduction has emerged as an energy-efficient and environmental-friendly technology to remove nitrate from water. Recently, non-noble metal electrocatalysts have attracted increasing attention in nitrate reduction due to their great advantages in terms of low cost, high activity, and large-scale application potential. This review highlights the latest research progress in the area of non-noble metal materials for electrochemical nitrate reduction. The mechanistic insight into the electrochemical reduction of nitrate is briefly discussed. Meanwhile, numerous examples in this field are collected and analyzed. Some strategies employed to improve the performance of nitrate electroreduction are also presented. Finally, the challenges and prospects in this field are discussed. This review hopes to guide the design and development of efficient non-noble metal electrocatalysts for nitrate reduction on a large scale.

引用

页数：16

共 129 条

[1] Ion-exchange polyHIPE type membrane for removing nitrate ions: Preparation, characterization, kinetics and adsorption studies [J].

Alikhani, M. ;

Moghbeli, M. R. .

CHEMICAL ENGINEERING JOURNAL, 2014, 239 :93-104

[2] A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements [J].

Andersen, Suzanne Z. ;

Colic, Viktor ;

Yang, Sungeun ;

Schwalbe, Jay A. ;

Nielander, Adam C. ;

McEnaney, Joshua M. ;

Enemark-Rasmussen, Kasper ;

Baker, Jon G. ;

Singh, Aayush R. ;

Rohr, Brian A. ;

Statt, Michael J. ;

Blair, Sarah J. ;

Mezzavilla, Stefano ;

Kibsgaard, Jakob ;

Vesborg, Peter C. K. ;

Cargnello, Matteo ;

Bent, Stacey F. ;

Jaramillo, Thomas F. ;

Stephens, Ifan E. L. ;

Norskov, Jens K. ;

Chorkendorff, Ib .

NATURE, 2019, 570 (7762) :504-+

[3] Electrocatalytic reduction of nitrate on copper electrode in alkaline solution [J].

Badea, Gabriela Elena .

ELECTROCHIMICA ACTA, 2009, 54 (03) :996-1001

[4] Nitrate adsorption and reduction on Cu(100) in acidic solution [J].

Bae, Sang-Eun ;

Stewart, Karen L. ;

Gewirth, Andrew A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (33) :10171-10180

[5] Electrochemical Restructuring of Copper Surfaces Using Organic Additives and Its Effect on the Electrocatalytic Reduction of Nitrate Ions [J].

Balkis, Ali ;

O'Mullane, Anthony P. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2015, 68 (08) :1213-1220

[6] Removal of boron, fluoride and nitrate by electrodialysis in the presence of organic matter [J].

Banasiak, Laura J. ;

Schaefer, Andrea I. .

JOURNAL OF MEMBRANE SCIENCE, 2009, 334 (1-2) :101-109

[7] Structural and electronic effects in heterogeneous electrocatalysis: Toward a rational design of electrocatalysts [J].

Bandarenka, Aliaksandr S. ;

Koper, Marc T. M. .

JOURNAL OF CATALYSIS, 2013, 308 :11-24

[8] Catalytic nitrate removal from water, past, present and future perspectives [J].

Barrabes, Noelia ;

Sa, Jacinto .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 104 (1-2) :1-5

[9] A review of emerging adsorbents for nitrate removal from water [J].

Bhatnagar, Amit ;

Sillanpaa, Mika .

CHEMICAL ENGINEERING JOURNAL, 2011, 168 (02) :493-504

[10] Nitrate reduction pathways on Cu single crystal surfaces: Effect of oxide and Cl- [J].

Butcher, Dennis P., Jr. ;

Gewirth, Andrew A. .

NANO ENERGY, 2016, 29 :457-465

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