Preparation and Characterization of Cu-doped ZnO Sol-gel Derived Optical Thin films

被引:4
作者
Chongsri, Krisana [1 ]
Aunpang, Siriwattana [2 ]
Techitdheera, Wicharn [2 ]
Pecharapa, Wisanu [3 ,4 ]
机构
[1] Rajabhat Rajanagarindra Univ, Fac Sci & Technol, Dept Appl Phys, Chachoengsao 24000, Thailand
[2] King Mongkuts Inst Technol Ladkrabang, Sch Appl Phys, Bangkok 10520, Thailand
[3] King Mongkuts Inst Technol Ladkrabang, Coll Nanotechnol, Bangkok 10520, Thailand
[4] ThEP Ctr, Bangkok 10400, Thailand
来源
ADVANCES IN MATERIAL SCIENCE AND TECHNOLOGY | 2013年 / 802卷
关键词
Cu-doped ZnO; Thin films; Sol-gel method;
D O I
10.4028/www.scientific.net/AMR.802.124
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, we report the preparation of Cu-doped ZnO thin films by sol-gel method based on zinc acetate dihydrate (CH3COO)(2)Zn center dot 2H(2)O, Copper acetate dihydrate Cu-3(CH3COO)(2)center dot H2O) and diethanolamine (HN(CH2OH)(2), DEA). The precursor solution was prepared at various Cu composition ranging from 2-20 wt%. All films were spin-coated on borosilicate substrates for several coating repetition followed by annealing process at 550 degrees C for 4 h in an ambient air. The structural properties of the films were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The XRD results indicate the domination of hexagonal wurtzite structure of ZnO with noticeable alternation in the XRD peak intensity upon Cu doping content. SEM results revealed the grain size shape and surface morphologies of as-prepared samples. Crucial optical properties of as-prepared films were scrutinized from their UV-Vis transmission spectra. The films are highly transparent in the visible region with more than 90 % transparency within 380 nm to 800 nm. Their corresponding band gaps indicate significant red shift with increasing Cu doping content. Overall results suggest that Cu additive play a vital role on relevant optical properties of ZnO that can be adjusted to meet the requirement for practical optoelectronics applications.
引用
收藏
页码:124 / +
页数:2
相关论文
共 13 条
[1]   Effects of Mn and Cu Edoping on the microstructures and optical properties of sol-gel derived ZnO thin films [J].
Bahsi, Z. Banu ;
Oral, A. Yavuz .
OPTICAL MATERIALS, 2007, 29 (06) :672-678
[2]   Structural and optical properties of copper doped ZnO films derived by sol-gel [J].
Caglar, M. ;
Yakuphanoglu, F. .
APPLIED SURFACE SCIENCE, 2012, 258 (07) :3039-3044
[3]   Room temperature ferromagnetism in nanocrystalline Ni-doped ZnO synthesized by co-precipitation [J].
El-Hilo, M. ;
Dakhel, A. A. ;
Ali-Mohamed, A. Y. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (14) :2279-2283
[4]   Zinc magnesium oxide nanofibers on glass substrate by solution growth technique [J].
Gayen, R. N. ;
Das, S. N. ;
Dalui, S. ;
Bhar, R. ;
Pal, A. K. .
JOURNAL OF CRYSTAL GROWTH, 2008, 310 (18) :4073-4080
[5]   Optical properties and luminescence of metallic nanoclusters in ZnO:Cu [J].
Karali, T ;
Can, N ;
Valberg, L ;
Stepanov, AL ;
Townsend, PD ;
Buchal, C ;
Ganeev, RA ;
Ryasnyansky, AI ;
Belik, HG ;
Jessett, ML ;
Ong, C .
PHYSICA B-CONDENSED MATTER, 2005, 363 (1-4) :88-95
[6]   Spray pyrolysis deposition of zinc oxide nanostructured layers [J].
Krunks, M. ;
Dedova, T. ;
Acik, I. Oja .
THIN SOLID FILMS, 2006, 515 (03) :1157-1160
[7]   Effects of thermal annealing on the structural and optical properties E of MgxZn1-xO nanocrystals [J].
Li, JH ;
Liu, YC ;
Shao, CL ;
Zhang, XT ;
Shen, DZ ;
Lu, YM ;
Zhang, JY ;
Fan, XW .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 283 (02) :513-517
[8]   Influence of doping concentrations on the aluminum doped zinc oxide thin films properties for ultraviolet photoconductive sensor applications [J].
Mamat, M. H. ;
Sahdan, M. Z. ;
Khusaimi, Z. ;
Ahmed, A. Zain ;
Abdullah, S. ;
Rusop, M. .
OPTICAL MATERIALS, 2010, 32 (06) :696-699
[9]   Crystallite size dependence of band gap energy for electrodeposited ZnO grown at different temperatures [J].
Marotti, R. E. ;
Giorgi, P. ;
Machado, G. ;
Dalchiele, E. A. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (15) :2356-2361
[10]  
Mustafa O., 2008, THIN SOLID FILMS, V516, P1703