One-electron oxidation of metal enolates and metal phenolates

被引：34
作者：
Schmittel, M [1 ]
Haeuseler, A [1 ]
机构：
[1] Univ Siegen, D-57068 Siegen, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 661卷 / 1-2期
关键词：
metal enolate; metal phenolate; radical cation; bond cleavage; stereoselectivity; kinetics;
D O I：
10.1016/S0022-328X(02)01823-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure and reactivity of a large number of metal enolates/metal phenolates and their radical cations is analyzed from both a preparative and mechanistic point of view. Special attention is given to the M-O bond cleavage and the C-C coupling on the stage of the radical cations. The insight obtained allowed to devise a novel selective oxidative coupling of enolates and phenolates through an intramolecular variant. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：169 / 179
页数：11
相关论文
共 50 条
  • [41] Electron transfer fluorescence quenching of napthalenediols by metal ions
    Radha, Nachiappan
    Swaminathan, Meenakshisundaram
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2018, 57 (07): : 915 - 919
  • [42] Electron Transfer Drives Metal Cycling in the Critical Zone
    Davranche, Melanie
    Gelabert, Alexandre
    Benedetti, Marc F.
    ELEMENTS, 2020, 16 (03) : 185 - 190
  • [43] One-electron oxidation of diclofenac by human cytochrome P450s as a potential bioactivation mechanism for formation of 2′-(glutathion-S-yl)-deschloro-diclofenac
    Boerma, Jan Simon
    Vermeulen, Nico P. E.
    Commandeur, Jan N. M.
    CHEMICO-BIOLOGICAL INTERACTIONS, 2014, 207 : 32 - 40
  • [44] Examination of Water Oxidation by Catalysts Containing Cofacial Metal Sites
    Wasylenko, Derek J.
    Ganesamoorthy, Chelladurai
    Koivisto, Bryan D.
    Berlinguette, Curtis P.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (20) : 3135 - 3142
  • [45] Kinetics of oxidation of L-cysteine by transition metal complexes
    Abdel-Halim, HM
    Abu-Surrah, AS
    Qaqish, SE
    ASIAN JOURNAL OF CHEMISTRY, 2006, 18 (02) : 947 - 956
  • [46] Engineering aspects of the aqueous noble metal catalysed alcohol oxidation
    Kluytmans, JHJ
    Markusse, AP
    Kuster, BFM
    Marin, GB
    Schouten, JC
    CATALYSIS TODAY, 2000, 57 (1-2) : 143 - 155
  • [47] Simultaneous Oxidation and Metal Dusting of Fe-Si Alloys
    Motin, M. A. A.
    Zhang, J.
    Young, D. J.
    HIGH TEMPERATURE CORROSION AND MATERIALS CHEMISTRY 8, 2010, 25 (25): : 57 - 69
  • [48] Departures from local interfacial equilibrium during metal oxidation
    Ramanathan, Rohit
    Voorhees, Peter W.
    PHYSICAL REVIEW MATERIALS, 2020, 4 (11):
  • [49] Internal oxidation and metal dusting of Fe-Si alloys
    Motin, M. A. A.
    Zhang, J.
    Munroe, P. R.
    Young, D. J.
    CORROSION SCIENCE, 2010, 52 (10) : 3280 - 3286
  • [50] Interfacial Tension Modulation of Liquid Metal via Electrochemical Oxidation
    Song, Minyung
    Daniels, Karen E.
    Kiani, Abolfazl
    Rashid-Nadimi, Sahar
    Dickey, Michael D.
    ADVANCED INTELLIGENT SYSTEMS, 2021, 3 (08)
12345