Allelochemicals from New Zealand fungi -: (+)-Brevione A.: The first member of a novel family of bioactive spiroditerpenoids isolated from Penicillium brevicompactum Dierckx

被引：44

作者：

Macías, FA

Varela, RM

Simonet, AM

Cutler, HG

Cutler, SJ

Ross, SA

Dunbar, DC

Dugan, FM

Hill, RA

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Cadiz 11510, Spain

[2] Mercer Univ, So Sch Pharm, Atlanta, GA 30341 USA

[3] Univ Mississippi, Sch Pharm, Natl Ctr Dev Nat Prod, University, MS 38677 USA

[4] Univ Mississippi, Sch Pharm, Dept Pharmacognosy, University, MS 38677 USA

[5] USDA, Western Reg Plant Intro Stn, Pullman, WA 99164 USA

[6] HortResearch, Ruakura Res Ctr, Hamilton, New Zealand

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 15期

关键词：

biologically active compound; allelochemical; terpenoid; Penicillium brevicompactum;

D O I：

10.1016/S0040-4039(00)00223-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+)-Brevione A, the first member of a novel family of bioactive spiroditerpenoids, a potential allelopathic agent, has been isolated from the ethyl acetate active fractions of the aqueous acetone extracts of semi-solid fermented Penicillium brevicompactum Dierckx. The structure displays the novel spiroditerpenoid skeleton of breviane. The structure elucidation of brevione A was performed by homo- and hetero-nuclear 2D NMR spectral data. On the basis of combined studies of the theoretical conformations and NOEDIFF data, its relative stereochemistry is proposed. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2683 / 2686

页数：4

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