[1] Open Univ, Dept Earth Sci, Milton Keynes MK7 6AA, Bucks, England
[2] Univ Lancaster, Dept Environm Sci, Lancaster LA1 4YQ, England
[3] Univ Edinburgh, Dept Geol & Geophys, Edinburgh EH9 3JW, Midlothian, Scotland
[4] British Geol Survey, Edinburgh EH9 3LA, Midlothian, Scotland
[5] NERC, Isotope Geosci Lab, Keyworth NG12 5GG, Notts, England