Double-faced micelles from water-soluble polymers

被引：162
作者：
Voets, Ilja K.
de Keizer, Arie
de Waard, Pieter
Frederik, Peter M.
Bomans, Paul H. H.
Schmalz, Holger
Walther, Andreas
King, Stephen M.
Leermakers, Frans A. M.
Stuart, Martien A. Cohen
机构：
[1] Univ Wageningen & Res Ctr, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands
[2] Univ Wageningen & Res Ctr, Wageningen NMR Ctr, NL-6703 HA Wageningen, Netherlands
[3] Univ Maastricht, NL-6229 ER Maastricht, Netherlands
[4] Univ Bayreuth, D-95440 Bayreuth, Germany
[5] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期
关键词：
block copolymers; complex coacervation; micelles; self-assembly;
D O I：
10.1002/anie.200601000
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Asymmetric disk-shaped Janus micelles form spontaneously and reversibly when simple water-soluble diblock copolymers in aqueous solutions are mixed. The combination of associative and segregative phase separation within one nanostructure results in a disk-shaped micelle with a complex coacervate core and an asymmetric water-swollen corona which is microphase-separated into two distinct domains or faces. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6673 / 6676
页数：4
相关论文
共 31 条
[1]   Mixed micelles and other structures in the solubilization of bilayer lipid membranes by surfactants [J].
Almgren, M .
BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 2000, 1508 (1-2) :146-163
[2]  
COHENSTUART MA, 1998, LANGMUIR, V14, P6846, DOI DOI 10.1021/LA980778M
[3]   Self-assembly of regular hollow icosahedra in salt-free catanionic solutions [J].
Dubois, M ;
Demé, B ;
Gulik-Krzywicki, T ;
Dedieu, JC ;
Vautrin, C ;
Désert, S ;
Perez, E ;
Zemb, T .
NATURE, 2001, 411 (6838) :672-675
[4]  
EMDONDS WF, 2006, MACROMOLECULES, V39, P4526
[5]   Janus micelles [J].
Erhardt, R ;
Böker, A ;
Zettl, H ;
Kaya, H ;
Pyckhout-Hintzen, W ;
Krausch, G ;
Abetz, V ;
Müller, AHE .
MACROMOLECULES, 2001, 34 (04) :1069-1075
[6]   MODEL-CALCULATIONS ON THE TRANSITIONS BETWEEN SURFACTANT AGGREGATES OF DIFFERENT SHAPES [J].
ERIKSSON, JC ;
LJUNGGREN, S .
LANGMUIR, 1990, 6 (05) :895-904
[7]   Cryoelectron microscopy of liposomes [J].
Frederik, PM ;
Hubert, DHW .
LIPOSOMES, PT E, 2005, 391 :431-+
[8]   Triblock terpolymer micelles: A personal outlook [J].
Fustin, CA ;
Abetz, V ;
Gohy, JF .
EUROPEAN PHYSICAL JOURNAL E, 2005, 16 (03) :291-302
[9]   Water-soluble complexes formed by poly(2-vinylpyridinium)-block-poly(ethylene oxide) and poly(sodium methacrylate)-block-poly(ethylene oxide) copolymers [J].
Gohy, JF ;
Varshney, SK ;
Jérôme, R .
MACROMOLECULES, 2001, 34 (10) :3361-3366
[10]   Segregation of coronal chains in micelles formed by supramolecular interactions [J].
Gohy, JF ;
Khousakoun, E ;
Willet, N ;
Varshney, SK ;
Jérôme, R .
MACROMOLECULAR RAPID COMMUNICATIONS, 2004, 25 (17) :1536-1539
1234