N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrOx under mild reaction conditions

被引：114
作者：
Cui, Xinjiang [1 ]
Zhang, Yan [1 ]
Deng, Youquan [1 ]
Shi, Feng [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 88期
关键词：
SUPERCRITICAL CARBON-DIOXIDE; METHANOL SYNTHESIS; CO2; HYDROGENATION; FORMYLATION; TRANSFORMATION; FORMATES; ACID; CU;
D O I：
10.1039/c4cc05119j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H-2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.
引用
收藏
页码：13521 / 13524
页数：4
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