N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrOx under mild reaction conditions

被引：114

作者：

Cui, Xinjiang ^{[1
]}

Zhang, Yan ^{[1
]}

Deng, Youquan ^{[1
]}

Shi, Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 88期

关键词：

SUPERCRITICAL CARBON-DIOXIDE; METHANOL SYNTHESIS; CO2; HYDROGENATION; FORMYLATION; TRANSFORMATION; FORMATES; ACID; CU;

D O I：

10.1039/c4cc05119j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H-2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.

引用

页码：13521 / 13524

页数：4

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