Ionic conductive copolymer encapsulated graphite as an anode material for lithium ion batteries

被引：30

作者：

Pan, QM ^{[1
]}

Guo, KK ^{[1
]}

Wang, LZ ^{[1
]}

Fang, SB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

SOLID STATE IONICS | 2002年 / 149卷 / 3-4期

关键词：

lithium ion batteries; graphite anode; encapsulation; ionic conductive copolymer;

D O I：

10.1016/S0167-2738(02)00278-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In order to reduce the irreversible capacity and enhance the cycling life of the natural graphite anode of lithium ion batteries, a novel modification method was proposed by encapsulation with an ionically conductive co-polymer on the surface of natural graphite particles via radiation-initiated polymerization. The encapsulated graphite shows great improvement in electrochemical performance such as initial coulombic efficiency and cycleability compared with the original natural graphite. Raman spectroscopy indicates that encapsulation with an ionic conductive polymer can depress the structural changes caused by the cointercalation of solvent molecules. Stable electrode impedance during the repeated cycling is revealed by impedance spectra for encapsulated graphite. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：193 / 200

页数：8

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