Chiral bisimidazolium salts derived from amino acids and their palladium(II)- and platinum(II)-biscarbene complexes

被引：34

作者：

Meyer, Anke ^{[1
]}

Taige, Maria A. ^{[1
]}

Strassner, Thomas ^{[1
]}

机构：

[1] Tech Univ Dresden, D-01062 Dresden, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 12期

关键词：

Chiral bisimidazolium salts; Amino acids; N-heterocyclic carbene metal complexes; Palladium; Platinum; Solid state structure; N-HETEROCYCLIC CARBENES; METAL-COMPLEXES; STEREODIRECTING LIGANDS; STRUCTURAL-CHARACTERIZATION; ASYMMETRIC HYDROGENATION; BISCARBENE COMPLEXES; CATALYZED REACTIONS; CONJUGATE ADDITION; IONIC LIQUIDS; METHANE;

D O I：

10.1016/j.jorganchem.2009.01.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report new chiral bisimidazolium salts synthesized from naturally occurring L-amino acids. They served as precursors for bidentate N-heterocyclic carbene metal complexes. The chiral imidazoles could be synthesized in good yields via a one-pot ring closing reaction, followed by esterification. The methylene bridged bisimidazolium iodide salts are accessible in moderate yields. Corresponding palladium(II) and platinum(II)-NHC complexes could be synthesized and fully characterized, but do not show optical activity. We also report a solid state structure of one of the synthesized palladium(II) biscarbene compounds derived from alanine. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1861 / 1868

页数：8

共 50 条

[31] Cyclometallated platinum(II) compounds with imine ligands derived from amino acids: Synthesis and oxidative addition reactions
Rodriguez, Judit
Zafrilla, Javier
Albert, Joan
Crespo, Margarita
Granell, Jaume
Calvet, Teresa
Font-Bardia, Merce
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (16) : 2467 - 2475
[32] Bimetallic copper(II) and zinc(II) complexes of acyclic Schiff base ligands derived from amino acids
Arbaoui, Abdessamad
Redshaw, Carl
Sanchez-Ballester, Noelia M.
Elsegood, Mark R. J.
Hughes, David L.
INORGANICA CHIMICA ACTA, 2011, 365 (01) : 96 - 102
[33] New aliphatic and aromatic thiolato-bridged complexes of palladium(II) and platinum(II)
Ruiz, J
Vicente, C
Rodriguez, V
Lopez, G
POLYHEDRON, 1998, 17 (09) : 1503 - 1509
[34] Synthesis and structure of platinum(II)- and palladium(II)-phosphorin complexes in solid and solution state
Shiotsuka, Michito
Tanamachi, Takahiro
Urakawa, Tsuyoshi
Matsuda, Yoshihisa
JOURNAL OF MOLECULAR STRUCTURE, 2006, 794 (1-3) : 215 - 220
[35] Palladium(II) and platinum(II) tetramethyltetrapyridinoporphyrazine complexes: Redox properties and interactions with cysteine and histidine
Sekota, M
Nyokong, T
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 1999, 3 (6-7) : 477 - 487
[36] Heterobimetallic platinum(II)-palladium(II) complexes bridged by fluorobenzenethiolates. Structure and equilibria
Rivera, Guillermina
Bernes, Sylvain
Rodriguez de Barbarin, Cecilia
Torrens, Hugo
INORGANICA CHIMICA ACTA, 2009, 362 (14) : 5122 - 5125
[37] Platinum(II), palladium(II), and gold(III) complexes of dianionic, secondary dithiooxamide ligands
Tang, Haiming
Saunders, Graham C.
Henderson, William
JOURNAL OF COORDINATION CHEMISTRY, 2019, 72 (15) : 2550 - 2561
[38] Structural investigations of sulfite-bridged binuclear complexes of platinum(II) and palladium(II)
Krieglstein, R
Breitinger, DK
Liehr, G
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (12) : 3067 - 3072
[39] Synthesis, characterization, and cytotoxicities of palladium(II) and platinum(II) complexes containing fluorinated pyridinecarboxaldimines
Scales, SJ
Zhang, HW
Chapman, PA
McRory, CP
Derrah, EJ
Vogels, CM
Saleh, MT
Decken, A
Westcott, SA
POLYHEDRON, 2004, 23 (13) : 2169 - 2176
[40] The chemistry of tri- and high-nuclearity palladium(II) and platinum(II) complexes
Jain, Vimal K.
Jain, Leela
COORDINATION CHEMISTRY REVIEWS, 2010, 254 (23-24) : 2848 - 2903

← 1 2 3 4 5 →