The effect of production method on the properties of high impact polystyrene and polyaniline membranes

被引:15
作者
Amado, Franco D. R. [1 ,2 ]
Rodrigues, Marco A. S. [3 ]
Bertuol, Daniel A. [3 ]
Bernardes, Andrea M. [2 ]
Ferreira, Jane Z. [2 ]
Ferreira, Carlos A. [2 ]
机构
[1] Univ Estadual Santa Cruz, DCET Rodovia Ilheus Itabuna, BR-45662000 Ilheus, BA, Brazil
[2] Univ Fed Rio Grande do Sul, PPGEM, BR-91501970 Porto Alegre, RS, Brazil
[3] Ctr Univ Feevale, BR-93352000 Novo Hamburgo, RS, Brazil
关键词
Membrane; Electrodialysis; Mechanical mixture; Dissolution; TRANSPORT-PROPERTIES; CONTACT;
D O I
10.1016/j.memsci.2008.12.065
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, different membranes were prepared using conventional polymer (high impact polystyrene) and polyaniline to evaluate their use in electrodialysis. Two different preparation modes were tested: chemical mixture with subsequent solvent evaporation; and mechanical mixture with subsequent pressing under heating. The purpose was to understand the effect of production methods on membrane microstructure and ionic transport. Membranes were characterized by swelling study, Fourier transformed infrared spectroscopic, scanning electron microscopy, thermogravimetric analysis and dynamic mechanical analysis. Ionic transport through the membranes was evaluated using a three-compartment cell. The results of the produced membranes were compared with those of the commercial Nafion 450 membrane. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:227 / 232
页数:6
相关论文
共 23 条
[1]   Properties evaluation of the membranes synthesized with castor oil polyurethane and polyaniline [J].
Amado, F. D. R. ;
Rodrigues, L. F., Jr. ;
Forte, M. M. C. ;
Ferreira, C. A. .
POLYMER ENGINEERING AND SCIENCE, 2006, 46 (10) :1485-1489
[2]   Development of polyurethane/polyaniline membranes for zinc recovery through electrodialysis [J].
Amado, FDR ;
Rodrigues, LF ;
Rodrigues, MAS ;
Bernardes, AM ;
Ferreira, JZ ;
Ferreira, CA .
DESALINATION, 2005, 186 (1-3) :199-206
[3]   Synthesis and characterisation of high impact polystyrene/poly aniline composite membranes for electrodialysis [J].
Amado, FDR ;
Gondran, E ;
Ferreira, JZ ;
Rodrigues, MAS ;
Ferreira, CA .
JOURNAL OF MEMBRANE SCIENCE, 2004, 234 (1-2) :139-145
[4]  
[Anonymous], 1995, HDB IND MEMBRANES
[5]  
BARRA GMO, 2002, SYNTHETIC MET, V9271, P1
[6]   COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE AND OF CONDUCTING POLYBLENDS OF POLYANILINE IN BULK POLYMERS [J].
CAO, Y ;
SMITH, P ;
HEEGER, AJ .
SYNTHETIC METALS, 1992, 48 (01) :91-97
[7]   Transport of trivalent and hexavalent chromium through different ion-selective membranes in acidic aqueous media [J].
Dalla Costa, RF ;
Rodrigues, MAS ;
Ferreira, JZ .
SEPARATION SCIENCE AND TECHNOLOGY, 1998, 33 (08) :1135-1143
[8]   PROCESSABLE FORMS OF CONDUCTIVE POLYANILINE [J].
DAVIES, SJ ;
RYAN, TG ;
WILDE, CJ ;
BEYER, G .
SYNTHETIC METALS, 1995, 69 (1-3) :209-210
[9]   Comparison of transport properties of monovalent anions through anion-exchange membranes [J].
Elattar, A ;
Elmidaoui, A ;
Pismenskaia, N ;
Gavach, C ;
Pourcelly, G .
JOURNAL OF MEMBRANE SCIENCE, 1998, 143 (1-2) :249-261
[10]  
GALLAGHER PK, 1997, THERMAL CHARACTERIZA, P2