A compact QCL based methane and nitrous oxide sensor for environmental and medical applications

被引:85
作者
Jahjah, Mohammad [1 ]
Ren, Wei [1 ]
Stefanski, Przemyslaw [1 ]
Lewicki, Rafal [1 ]
Zhang, Jiawei [1 ,3 ]
Jiang, Wenzhe [1 ]
Tarka, Jan [1 ,2 ]
Tittel, Frank K. [1 ]
机构
[1] Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA
[2] Wroclaw Univ Technol, Laser & Fiber Elect Grp, PL-50370 Wroclaw, Poland
[3] Northeast Forestry Univ, Sch Electromech Engn, Harbin 150040, Heilongjiang Pr, Peoples R China
基金
美国国家科学基金会;
关键词
QUANTUM CASCADE LASERS; GREENHOUSE GASES; N2O;
D O I
10.1039/c3an01452e
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A methane (CH4) and nitrous oxide (N2O) sensor based on a sensitive, selective and well established technique of quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for environmental and biomedical measurements. A thermoelectrically cooled (TEC) distributed feedback quantum cascade laser (DFB-QCL), capable of continuous wave (CW) mode hop free emission in the 7.83 mu m wavelength range, was used as an excitation source. For the targeted CH4 and N2O absorption lines located at 1275.04 cm(-1) and 1275.49 cm(-1) detection limits (1 sigma) of 13 ppbv and 6 ppbv were achieved with a 1 second data acquisition time, respectively. Environmental data of CH4 and N2O mixing ratios acquired using the QEPAS sensor system are also reported.
引用
收藏
页码:2065 / 2069
页数:5
相关论文
共 29 条
[1]  
[Anonymous], 2009, GUID US NITR OX PED, V33, P190
[2]  
Austin M., 2012, ACAD DENT LEARN OSHA, P21
[3]  
Castillo P. C., 2013, P SOC PHOTO-OPT INS, V8718
[4]   Compact QEPAS sensor for trace methane and ammonia detection in impure hydrogen [J].
Dong, L. ;
Wright, J. ;
Peters, B. ;
Ferguson, B. A. ;
Tittel, F. K. ;
McWhorter, S. .
APPLIED PHYSICS B-LASERS AND OPTICS, 2012, 107 (02) :459-467
[5]   Ultra-sensitive carbon monoxide detection by using EC-QCL based quartz-enhanced photoacoustic spectroscopy [J].
Dong, L. ;
Lewicki, R. ;
Liu, K. ;
Buerki, P. R. ;
Weida, M. J. ;
Tittel, F. K. .
APPLIED PHYSICS B-LASERS AND OPTICS, 2012, 107 (02) :275-283
[6]   QEPAS spectrophones: design, optimization, and performance [J].
Dong, L. ;
Kosterev, A. A. ;
Thomazy, D. ;
Tittel, F. K. .
APPLIED PHYSICS B-LASERS AND OPTICS, 2010, 100 (03) :627-635
[7]  
Faist J., 2013, Quantum Cascade Lasers
[8]   Recent progress in quantum cascade lasers and applications [J].
Gmachl, C ;
Capasso, F ;
Sivco, DL ;
Cho, AY .
REPORTS ON PROGRESS IN PHYSICS, 2001, 64 (11) :1533-1601
[9]   A QEPAS based methane sensor with a 2.35 μm antimonide laser [J].
Jahjah, M. ;
Vicet, A. ;
Rouillard, Y. .
APPLIED PHYSICS B-LASERS AND OPTICS, 2012, 106 (02) :483-489
[10]   Exchange of the Greenhouse Gases Methane and Nitrous Oxide Between the Atmosphere and a Temperate Peatland in Central Europe [J].
Juszczak, Radosaw ;
Augustin, Juergen .
WETLANDS, 2013, 33 (05) :895-907