High resolution infrared spectra of 17O enriched ozone isotopic species in the 5 μm range: The ν1+ ν3 bands of 17O3, 17O16O17O, 16O17O17O and 17O17O18O

被引:1
作者
Barbe, Alain [1 ]
Starikova, Evgeniya [2 ,3 ]
机构
[1] UFR Sci Exactes & Nat, UMR CNRS 7331, Grp Spectrometrie Mol & Atmospher, Moulin Housse,BP 1039, F-51687 Reims 2, France
[2] VE Zuev Inst Atmospher Opt SB RAS, Lab Theoret Spect, 1 Academician Zuev Sq, Tomsk 634055, Russia
[3] Tomsk State Univ, Lab Quantum Mech Mol & Radiat Proc, 36 Lenin Ave, Tomsk 634050, Russia
关键词
Ozone; Isotopologues; C-s symmetry; nu(1) +nu(3) bands; FTS spectra; Resonance coupling; Effective Hamiltonian model; CW-CRDS SPECTRA; MASS-INDEPENDENT FRACTIONATION; LINE POSITIONS; O-16/O-18; ISOTOPOLOGUES; CONTACT TRANSFORMATIONS; TEMPERATURE-DEPENDENCE; EXCHANGE-REACTION; HEAVY OZONE; CAVITY RING; NU-3; BANDS;
D O I
10.1016/j.jqsrt.2019.04.027
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In a mixture of 18 isotopic species of ozone including O-17, O-16 and O-18 oxygen atoms, four nu(1) +nu(3) bands of O-17(3), (OO18)-O-17-O-17 O, (OOO)-O-16-O-17-O-17, (OOO)-O-17-O-16-O-17 in the 5 mu m range are analyzed for the first time. The analyses, accounting for interactions between (101) with (002) and (200) states permitted to assign respectively 747 transitions for (OOO)-O-17-O-17-O-18, 705 transitions for (OOO)-O-17-O-16-O-17, 889 transitions for (OO)-O-1-O-6-O-1-O-7 O-17 and 1404 transitions for O-17(3). The results of fits of effective Hamiltonian and transition moment parameters permit reproducing observed transitions within experimental accuracy. They allow to calculate synthetic spectra in excellent agreement with the observed ones. The band centers and rotational constants derived from experimental spectra are in good agreement with recent theoretical predictions from potential energy surfaces. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:116 / 125
页数:10
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