Fabrication of Cr2S3-GO-TiO2 composite with high visible-light-driven photocatalytic activity on degradation of organic dyes

被引:24
作者
Hasan, Jaafar [1 ,2 ]
Li, Haidi [1 ]
Tian, Guang [1 ]
Qin, Chuanguang [1 ]
机构
[1] Northwestern Polytech Univ, Key Lab Supernormal Mat Phys & Chem, Shaanxi Key Lab Polymer Sci & Technol, Minist Educ,Dept Chem,Sch Chem & Chem Engn, Xian 710129, Peoples R China
[2] AL Muthanna Univ, Coll Dent, Samawah, Al Muthanna Pro, Iraq
基金
中国国家自然科学基金;
关键词
Photocatalysis; Cr2S3; TiO2; Graphene oxide; Organic dye; Water treatment; GRAPHENE OXIDE/TIO2 COMPOSITES; MOS2; NANOSHEETS; PERFORMANCE; NANOCOMPOSITES; NANOPARTICLES; HYBRID; GRAPHITE; REMOVAL; ZNO;
D O I
10.1016/j.chemphys.2020.110950
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ternary compound photocatalyst (Cr2S3-GO/TiO2 composite) was prepared by combining graphene oxide (GO) and titanium oxide (TiO2) via sol-gel technique. This synthesized composite was characterized by various methods of analysis (XPS, XRD, SEM, EDX, BET, TGA and TEM). The as-synthesized composite exhibited enhanced photocatalytic performance and degradation rate yielded 98.3, 96.6 and 86.3% on methylene blue, rhodamine B and methyl orange, respectively, under the visible light for 120 min. Cr2S3-GO/TiO2 composite achieved the best photocatalytic activity with 0.3 mol of TiO2. This might be due to the collaborative interaction between increased defects of graphene oxide and photocatalytic effect of Cr2S3. Kinetic model data best fitted with pseudo-first-order model with regression coefficient values of R-2 >= 0.96. This provides a good opportunity for increased photocatalytic activity in the treatment of wastewater from organic pollutants.
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页数:10
相关论文
共 56 条
  • [1] Three-Dimensional Ordered Assembly of Thin-Shell Au/TiO2 Hollow Nanospheres for Enhanced Visible-Light-Driven Photocatalysis
    Cao-Thang Dinh
    Yen, Hoang
    Kleitz, Freddy
    Trong-On Do
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (26) : 6618 - 6623
  • [2] Correlation preparation parameters/activity for microTiO2 decorated with SilverNPs for NOx photodegradation under LED light
    Cerrato, Giuseppina
    Galli, Federico
    Boffito, Daria C.
    Operti, Lorenza
    Bianchi, Claudia L.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 253 : 218 - 225
  • [3] In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries
    Chang, Kun
    Chen, Weixiang
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (14) : 4252 - 4254
  • [4] Synthesis of Visible-Light Responsive Graphene Oxide/TiO2 Composites with p/n Heterojunction
    Chen, Chao
    Cai, Weimin
    Long, Mingce
    Zhou, Baoxue
    Wu, Yahui
    Wu, Deyong
    Feng, Yujie
    [J]. ACS NANO, 2010, 4 (11) : 6425 - 6432
  • [5] Porous peanut-like Bi2O3-BiVO4 composites with heterojunctions: one-step synthesis and their photocatalytic properties
    Chen, Lang
    Zhang, Qiang
    Huang, Rui
    Yin, Shuang-Feng
    Luo, Sheng-Lian
    Au, Chak-Tong
    [J]. DALTON TRANSACTIONS, 2012, 41 (31) : 9513 - 9518
  • [6] The Fabrication, Properties, and Uses of Graphene/Polymer Composites
    Du, Jinhong
    Cheng, Hui-Ming
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2012, 213 (10-11) : 1060 - 1077
  • [7] Synthesis and Characterization of Graphene Oxide/Zinc Oxide (GO/ZnO) Nanocomposite and Its Utilization for Photocatalytic Degradation of Basic Fuchsin Dye
    Durmus, Zehra
    Kurt, Belma Zengin
    Durmus, Ali
    [J]. CHEMISTRYSELECT, 2019, 4 (01): : 271 - 278
  • [8] Fujishima A., 2000, J PHOTOCH PHOTOBIO C, V1, P1, DOI [DOI 10.1016/S1389-5567(00)00002-2, 10.1016/S1389-5567(00)00002-2]
  • [9] The synergetic effect of sulfonated graphene and silver as co-catalysts for highly efficient photocatalytic hydrogen production of ZnO nanorods
    Gao, Peng
    Liu, Zhaoyang
    Sun, Darren Delai
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (45) : 14262 - 14269
  • [10] Photocatalytic removal of tetrabromobisphenol A by magnetically separable flower-like BiOBr/BiOI/Fe3O4 hybrid nanocomposites under visible-light irradiation
    Gao, Shengwang
    Guo, Changsheng
    Hou, Song
    Wan, Li
    Wang, Qiang
    Lv, Jiapei
    Zhang, Yuan
    Gao, Jianfeng
    Meng, Wei
    Xu, Jian
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2017, 331 : 1 - 12