Synthesis and crystal structures for two kinds of complexes of manganese(II)

被引:0
作者
Zhuo Xin [1 ]
Li Yi-Zhi
机构
[1] Suzhou Coll, Photoelect Chem Lab, Suzhou 234000, Anhui, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
关键词
Mn complex; 2-pyrazinecaboxylic acid; crystal structure;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two novel 3D coordination ploymers [Mn-2(Pyzca)(2)Cl-2](n) (1) and [Mn-2(Pyzca)(2)Br,], (2) were synthesized by the hydrothermal reaction. The structures were characterized by elemental analysis, IR and single crystal X-ray diffraction. Crystallographic data of the title coordination polymers 1 and 2:1: C10H6N4Cl2Mn2, Triclinic, P (1) over bar, a = 0.616 4(17) nm, b = 0.768 6(2) nm, c = 1.394 6(4) nm, alpha = 78.47 6(5)degrees, beta = 81.40 7(5)degrees, gamma = 77.94 3(5)degrees, Z = 2, V = 0.629 1(3) nm(3); 2: C10H6N4O4Br2Mn2, Triclinic, P (1) over bar, a = 6.623 6(17) nm, b = 0.774 0(2) nm, c = 1.411 7(4) nm, alpha = 77.720(5)degrees, beta = 81.673(5)degrees, gamma = 79.000(5)degrees, Z = 2, V = 0.649 6(3) nm(3). The coordination polymers have both a three-dimensional structure networks. CCDC: 604729, 1; 604730, 2.
引用
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页码:1788 / 1792
页数:5
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