Improvements of Nano-TiO2 on the Long-Term Chloride Resistance of Concrete with Polymer Coatings

被引:29
作者
Li, Guo [1 ,2 ,3 ]
Cui, Hangyuan [1 ]
Zhou, Jiacheng [1 ]
Hu, Weijian [1 ]
机构
[1] China Univ Min & Technol, Jiangsu Key Lab Environm Impact & Struct Safety E, Xuzhou 221116, Jiangsu, Peoples R China
[2] China Univ Min & Technol, State Key Lab Geomech & Deep Underground Engn, Xuzhou 221116, Jiangsu, Peoples R China
[3] Jiangsu Vocat Inst Architectural Technol, Jiangsu Collaborat Innovat Ctr Bldg Energy Saving, Xuzhou 221116, Jiangsu, Peoples R China
关键词
concrete; polymer coatings; nano-TiO2; chloride resistance; aging; SURFACE-TREATMENT; CARBONATION RESISTANCE; ORGANIC COATINGS; PERFORMANCE; CORROSION; NANOCOMPOSITES; POLYURETHANE; EXPOSURE; BARRIER; SILICA;
D O I
10.3390/coatings9050323
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The long-term chloride resistance of concrete treated with nano-TiO2-modified polymer coatings was studied. Three types of organic film-forming paints: polyurethane, epoxy resin, and chlorinated rubber were selected, and concrete specimens with nano-TiO2-modified coatings were fabricated. Then, specimens were subjected to periodical ultraviolet-accelerated aging and subsequent Coulomb electric flux experiments. Nanomodified coatings before and after ultraviolet aging were observed through scanning electron microcopy. Results indicate that the nano-TiO2 particles can effectively reduce the microdefects in coating films and alleviate damages due to aging. As a result, nano-TiO2 can significantly reduce the Coulomb fluxes of coated concrete before and after coating aging, and the average reduction amplitudes reached 66% and 44%. That is, nano-TiO2 can remarkably improve the long-term chloride resistance of coated concrete. In addition, we established the development models of the ultraviolet aging and chloride resistance of coated concrete according to an S-shaped curve.
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页数:9
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