Cubosome description of the inorganic mesoporous structure MCM-48

被引:57
|
作者
Alfredsson, V
Anderson, MW
Ohsuna, T
Terasaki, O
Jacob, M
Bojrup, M
机构
[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND
[2] LUND UNIV,S-22100 LUND,SWEDEN
[3] TOHOKU UNIV,DEPT PHYS,SENDAI,MIYAGI 980,JAPAN
[4] ETH ZURICH,CH-8092 ZURICH,SWITZERLAND
[5] CAMURUS,S-22370 LUND,SWEDEN
关键词
D O I
10.1021/cm970052w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The cubic mesoporous hydroxylated silicate MCM-48 is shown to consist of sub-micronsized particles which display ''crystal-like'' faces. This well-defined particle habit is described in terms of cubosome behavior, and a complete representation of the particle structure is given as an analytical function. This function combines, in an exponential manner, both the minimal surface nature of the internal structure and the polyhedral nature of the peripheral structure. The consequences of a cubosome nature for MCM-48 are discussed in terms of possible chirality.
引用
收藏
页码:2066 / 2070
页数:5
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