A metastable β-type Zr-4Mo-4Sn alloy with low cost, low Young's modulus and low magnetic susceptibility for biomedical applications

被引:20
作者
Guo, Shun [1 ,2 ]
Shang, Yao [1 ]
Zhang, Jinming [1 ]
Zhang, Junsong [1 ]
Meng, Qingkun [3 ]
Cheng, Xiaonong [1 ]
Zhao, Xinqing [2 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
[2] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
[3] China Univ Min & Technol, Sch Mat Sci & Engn, Xuzhou 221116, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Biomaterials; Zr alloys; beta-type; Low elastic modulus; Low magnetic susceptibility; HARD-TISSUE REPLACEMENTS; CUBIC PHASE-STABILITY; NB-BASED ALLOYS; TITANIUM-ALLOYS; TI-ALLOYS; MECHANICAL-PROPERTIES; ELASTIC PROPERTIES; OMEGA PHASE; ZR; MO;
D O I
10.1016/j.jallcom.2018.04.279
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By alloying and thermo-mechanical treatment, a novel low-cost metastable beta-type Zr-4Mo-4Sn alloy was designed and fabricated for biomedical applications. Upon solution treatment plus quenching, the beta-type Zr-4Mo-4Sn alloy exhibits a combination of low Young's modulus (48 GPa) and low magnetic susceptibility (1.22 x 10(-6)cm(3)g(-1)). This low magnetic susceptibility (?) is reasonably attributed to the choice of alloying components with low ?, i.e., Zr (?(Zr) = 1-32 x 10(-6)cm(3)g(-1)), Mo (?(Mo) = 0.75 x 10(-6)cm(3) g(-1)) and Sn (?(Sn) = 0.03 x 10(-6)cm(3)g(-1)). An analysis of single-crystal elastic constants and Hill approximation indicated that in comparison to binary beta-type Ti-based alloys, the present beta-type Zr-4Mo-4Sn alloy possesses lower bcc-structural (?-phase) stability represented by its lower C' and much lower C-44, resulting in the ultralow Young's modulus of Zr-4Mo-4Sn alloy. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:232 / 237
页数:6
相关论文
共 32 条
[1]   General approach to phase stability and elastic properties of β-type Ti-alloys using electronic parameters [J].
Abdel-Hady, Mohamed ;
Hinoshita, Keita ;
Morinaga, Masahiko .
SCRIPTA MATERIALIA, 2006, 55 (05) :477-480
[2]   Biocompatibility of β-stabilizing elements of titanium alloys [J].
Eisenbarth, E ;
Velten, D ;
Müller, M ;
Thull, R ;
Breme, J .
BIOMATERIALS, 2004, 25 (26) :5705-5713
[3]   The interobserver-validated relevance of intervertebral spacer materials in MRI artifacting [J].
Ernstberger, T. ;
Heidrich, G. ;
Bruening, T. ;
Krefft, S. ;
Buchhorn, G. ;
Klinger, H. M. .
EUROPEAN SPINE JOURNAL, 2007, 16 (02) :179-185
[4]   RELATION OF C' ELASTIC MODULUS TO STABILITY OF BCC TRANSITION METALS [J].
FISHER, ES ;
DEVER, D .
ACTA METALLURGICA, 1970, 18 (02) :265-&
[5]   Ti based biomaterials, the ultimate choice for orthopaedic implants - A review [J].
Geetha, M. ;
Singh, A. K. ;
Asokamani, R. ;
Gogia, A. K. .
PROGRESS IN MATERIALS SCIENCE, 2009, 54 (03) :397-425
[6]   A novel metastable β-type Zr-12Nb-4Sn alloy with low Young's modulus and low magnetic susceptibility [J].
Guo, Shun ;
Zhang, Jinming ;
Shang, Yao ;
Zhang, Junsong ;
Meng, Qingkun ;
Cheng, Xiaonong ;
Zhao, Xinqing .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 745 :234-239
[7]   In situ synchrotron X-ray diffraction study of deformation behaviour of a metastable β-type Ti-33Nb-4Sn alloy [J].
Guo, Shun ;
Shang, Yao ;
Zhang, Junsong ;
Meng, Qingkun ;
Cheng, Xiaonong ;
Zhao, Xinqing .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2017, 692 :81-89
[8]   A metastable β-type Ti-Nb binary alloy with low modulus and high strength [J].
Guo, Shun ;
Zhang, Junsong ;
Cheng, Xiaonong ;
Zhao, Xinqing .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 644 :411-415
[9]   Suppression of isothermal ω phase by dislocation tangles and grain boundaries in metastable β-type titanium alloys [J].
Guo, Shun ;
Meng, Qingkun ;
Hu, Liang ;
Liao, Guangyue ;
Zhao, Xinqing ;
Xu, Huibin .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 550 :35-38
[10]   Effect of Zr and Sn on Young's modulus and superelasticity of Ti-Nb-based alloys [J].
Hao, Y. L. ;
Li, S. J. ;
Sun, S. Y. ;
Yang, R. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 441 (1-2) :112-118