Low-cost zinc complexes for white organic light-emitting devices

被引:51
作者
Dumur, Frederic [1 ,2 ,3 ]
Beouch, Layla [4 ]
Tehfe, Mohamad-Ali [5 ]
Contal, Emmanuel [3 ]
Lepeltier, Marc [6 ]
Wantz, Guillaume [1 ,2 ]
Graff, Bernadette [5 ]
Goubard, Fabrice [4 ]
Mayer, Cedric R. [7 ]
Lalevee, Jacques [5 ]
Gigmes, Didier [3 ]
机构
[1] Univ Bordeaux, IMS, UMR 5218, F-33400 Talence, France
[2] CNRS, IMS, UMR 5218, F-33400 Talence, France
[3] Aix Marseille Univ, CNRS, ICR, UMR 7273, F-13397 Marseille, France
[4] Univ Cergy Pontoise, LPPI, F-95031 Cergy Pontoise, France
[5] Univ Haute Alsace, Inst Sci Mat Mulhouse IS2M, UMR 7361, CNRS, F-68057 Mulhouse, France
[6] Univ Versailles St Quentin Yvelines, Inst Lavoisier Versailles, CNRS, UMR 8180, F-78035 Versailles, France
[7] Univ Versailles St Quentin Yvelines, Lab Ingn Syst Versailles, EA 4048, F-78140 Velizy Villacoublay, France
关键词
Zinc; Organic light emitting diodes; Electroluminescence; White; Blue; SCHIFF-BASE; ELECTROLUMINESCENT PROPERTIES; METAL-COMPLEXES; IRIDIUM COMPLEXES; CRYSTAL-STRUCTURE; BLUE; ZN(HPB)(2); PHOLEDS; LAYER; PHOTOPOLYMERIZATION;
D O I
10.1016/j.tsf.2014.06.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of blue fluorescent Zn (II) tetradentate Schiff base complexes has been designed and synthesized for applications in organic light-emitting diodes. The five complexes were investigated as dopant materials or as single emitters of multilayered p-i OLEDs. White OLEDs were achieved using these compounds as dopants of 4,4',4 ''-tris(N-carbazolyl)triphenylamine and best devices exhibited a high quality white-light emission with remarkable CIE (Commission Internationale de l'Eclairage) coordinates (0.33, 0.34). When used as single emitters, sky-blue and blue electroluminescent devices were prepared, except with one complex that gave yellow OLEDs. Optical properties of these complexes were examined by UV-visible absorption and luminescence spectroscopy. Their electrochemical properties are also reported. These results open the route to the development of cost-effective complexes for white organic light-emitting devices applications. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:351 / 360
页数:10
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