A highly asymmetric, Lewis acid-catalysed Diels-Alder reaction using optically active 2-(3-tolyl-p-sulfinyl)furyl alpha,beta-unsaturated ketones as a dienophile

被引：15

作者：

Arai, Y ^{[1
]}

Masuda, T ^{[1
]}

Masaki, Y ^{[1
]}

Shiro, M ^{[1
]}

机构：

[1] RIGAKU CORP,AKISHIMA,TOKYO 196,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 08期

关键词：

D O I：

10.1039/p19960000759

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of chiral 2-(3-tolyl-p-sulfinyl)furyl alpha,beta-unsaturated ketones 3 and 4 with cyclopentadiene in the presence of a Lewis acid proceeds smoothly to give the corresponding endo adducts 5a and 6a, respectively, in excellent yield with high diastereoselectivity.

引用

页码：759 / 762

页数：4

共 19 条

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