Facile Synthesis of Nitrogen-containing Polycyclic Aromatic Hydrocarbons from Perylene Bisimides

被引：6

作者：

Ito, Satoru ^{[1
]}

Hiroto, Satoru ^{[1
]}

Shinokubo, Hiroshi ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 08期

关键词：

ELECTRONIC-PROPERTIES; ORGANIC ELECTRONICS; FAMILY; IMIDES; AZINE;

D O I：

10.1246/cl.140330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have developed a facile procedure for the synthesis of pi-extended fluorubins from perylene bisimides. Iridium-catalyzed direct borylation, the Suzuki-Miyaura cross-coupling, and an acid-condensation sequence afforded pi-extended fluorubins 1 in moderate yields. X-ray diffraction analysis revealed a planar structure of 1. In addition, optical analysis and DFT calculations indicated the presence of intramolecular charge-transfer interactions in 1c.

引用

页码：1309 / 1311

页数：3