Equilibration of syn- and anti(Me)-[Co(mecyclen)(S-AlaO)](2+) isomers via one-ended dissociation of (S)-alanine

被引：1

作者：

Buckingham, DA

Clark, CR

Rogers, AJ

机构：

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 17期

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D O I：

10.1021/ic970118p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Equilibration of the syn(Me)/anti(Me) isomers of [Co(Mecyclen)(S-AlaO)](2+) in D2O is OD- catalyzed and occurs via opening up of the (S)-alaninato chelate and rechelation at an opposite octahedral face. This process is preferred over the usually observed OD--catalyzed epimerization at alpha-CHMe.

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页码：3791 / &

页数：4

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