A white emitting phosphor BaMg2(PO4)2:Ce3+, Mn2+, Tb3+: Luminescence and energy transfer

被引：34
作者：
Wang, Zhijun [1 ]
Li, Panlai [1 ]
Yang, Zhiping [1 ]
Guo, Qinglin [1 ]
Dong, Guoyi [1 ]
机构：
[1] Hebei Univ, Coll Phys Sci & Technol, Baoding 071002, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2014年 / 40卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Luminescence; Phosphors; EMISSION-TUNABLE PHOSPHOR; LIGHT-GENERATION; SINGLE-PHASE; CE3+;
D O I：
10.1016/j.ceramint.2014.07.026
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A single-phase white emitting phosphor BaMg2(PO4)(2):Ce3+, Mn2+, Tb3+ is synthesized by a high temperature solid-state reaction. There has a spectral overlap between emission band of Ce3+ and excitation bands of Mn2+ and Tb3+, which may support occurrence of energy transfer (ET) from Ce3+ to Mn2+ and Tb3+. Emitting color of BaMg2(PO4)(2):Ce3+, Mn2+, Tb3+ can be adjusted from blue to green via ET of Ce3+ -> Tb3+ and blue to red via ET of Ce3+ -> Mn2+, respectively. A white light emitting diode (white LED) is fabricated by combining a single-phase white emitting phosphor BMP:3%Ce3+, 5%Mn2+, 3%Tb3+ with a 365 nm LED chip, and CIE chromaticity coordinates and correlated color temperature (CCT) of the white LEDs are (0.312, 0.313) and 6217 K, respectively. Therefore, as white emitting phosphor, BaMg2(PO4)(2):Ce3+/Mn2+/Tb3+ may have potential application in white LEDs. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：15283 / 15292
页数：10
相关论文
共 41 条
  • [1] BLASSE G, 1969, PHILIPS RES REP, V24, P131
  • [2] Robust thermal performance of Sr2Si5N8:Eu2+: An efficient red emitting phosphor for light emitting diode based white lighting
    Brinkley, Stuart E.
    Pfaff, Nathan
    Denault, Kristin A.
    Zhang, Zhijun
    Hintzen, H. T.
    Seshadri, Ram
    Nakamura, Shuji
    DenBaars, Steven P.
    [J]. APPLIED PHYSICS LETTERS, 2011, 99 (24)
  • [3] Photoluminescence of Ce3+ and Mn2+ in zinc metaphosphate glasses
    Caldiño, U
    Hernández-Pozos, JL
    Flores, C
    Speghini, A
    Bettinelli, M
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (46) : 7297 - 7305
  • [4] Energy transfer in CaF2 doped with Ce3+, Eu 2+ and Mn2+ ions
    Caldiño, U.G.
    [J]. 2003, Institute of Physics Publishing (15) : 7127 - 7137
  • [5] Bright white upconversion luminescence in rare-earth-ion-doped Y2O3 nanocrystals
    Chen, G. Y.
    Liu, Y.
    Zhang, Y. G.
    Somesfalean, G.
    Zhang, Z. G.
    Sun, Q.
    Wang, F. P.
    [J]. APPLIED PHYSICS LETTERS, 2007, 91 (13)
  • [6] THEORY OF CONCENTRATION QUENCHING IN INORGANIC PHOSPHORS
    DEXTER, DL
    SCHULMAN, JH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (06) : 1063 - 1070
  • [7] STRONTIUM DICOBALT ORTHOPHOSPHATE
    ELBALI, B
    BOUKHARI, A
    HOLT, EM
    ARIDE, J
    [J]. JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1993, 23 (12): : 1001 - 1004
  • [8] Energy Transfer Mechanism and Luminescence of Ce0.67Tb0.33Mg1-xMnxAl11O19 Wide-Color-Gamut CCFL Green Phosphor
    Fang, Ying-Chien
    Huang, Xiao-Rong
    Lin, Han-Yu
    Chu, Sheng-Yuan
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (09) : 2735 - 2738
  • [9] Tunable luminescence and energy transfer properties of Ca5(PO4)2SiO4:Ce3+/Tb3+/Mn2+ phosphors
    Geng, Dongling
    Shang, Mengmeng
    Zhang, Yang
    Lian, Hongzhou
    Cheng, Ziyong
    Lin, Jun
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (12) : 2345 - 2353
  • [10] Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors
    Geng, Dongling
    Li, Guogang
    Shang, Mengmeng
    Yang, Dongmei
    Zhang, Yang
    Cheng, Ziyong
    Lin, Jun
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (28) : 14262 - 14271
12345