Spin crossover in iron(II) complexes: Recent advances

被引：58
作者：
Gaspar, A. B. [1 ]
Seredyuk, M. [2 ]
Guetlich, P. [2 ]
机构：
[1] Univ Valencia, ICMol, Dept Quim Inorgan, Valencia 46071, Spain
[2] Johannes Gutenberg Univ Mainz, Inst Anorgan & Analyt Chem, D-55099 Mainz, Germany
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 924卷
关键词：
Mossbauer spectroscopy; Spin crossover; Phase transition; MOLECULAR MATERIALS; MAGNETIC INTERACTION; DINUCLEAR COMPOUND; THERMAL HYSTERESIS; PHASE-TRANSITIONS; CRYSTAL-STRUCTURE; STATE; TEMPERATURE; BEHAVIOR; 2,2-BIPYRIMIDINE;
D O I：
10.1016/j.molstruc.2008.11.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this review article, several representative Multifunctional SCO materials exhibiting interplay/synergy between the spin transition and magnetic coupling or liquid crystalline properties together with the present pioneering works on nano-structuration of SCO materials are illustrated. As the Mossbauer spectroscopy has been decisive in the study of the physical properties of these multifunctional materials, special attention is given to their corresponding Mossbauer investigations. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：9 / 19
页数：11
相关论文
共 50 条
  • [21] Hydrophobic tail length in spin crossover active iron(ii) complexes predictably tunes T1/2 in solution and enables surface immobilisation
    Sundaresan, Sriram
    Kitchen, Jonathan A.
    Brooker, Sally
    INORGANIC CHEMISTRY FRONTIERS, 2020, 7 (10): : 2050 - 2059
  • [22] Iron(III) Azadiphenolate Compounds in a New Family of Spin Crossover Iron(II)-Iron(III) Mixed-Valent Complexes
    Phonsri, Wasinee
    Macedo, David S.
    Lewis, Barnaby A. I.
    Wain, Declan F.
    Murray, Keith S.
    MAGNETOCHEMISTRY, 2019, 5 (02)
  • [23] Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review
    Seredyuk, M. L.
    Znovjyak, K. O.
    Fritsky, I. O.
    THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2022, 58 (02) : 75 - 89
  • [24] Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review
    M. L. Seredyuk
    K. O. Znovjyak
    I. O. Fritsky
    Theoretical and Experimental Chemistry, 2022, 58 : 75 - 89
  • [25] Advances in polynuclear iron(II), iron(III) and cobalt(II) spin-crossover compounds
    Murray, Keith S.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 20 (20) : 3101 - 3121
  • [26] Spin crossover in 2D iron(ii) phthalazine cyanometallic complexes
    Hiiuk, Volodymyr M.
    Shova, Sergiu
    Rotaru, Aurelian
    Golub, Alexander A.
    Fritsky, Igor O.
    Gural'skiy, Il'ya A.
    DALTON TRANSACTIONS, 2020, 49 (16) : 5302 - 5311
  • [27] Spin crossover iron(II) complexes as PARACEST MRI thermometers
    Jeon, Ie-Rang
    Park, Jesse G.
    Haney, Chad R.
    Harris, T. David
    CHEMICAL SCIENCE, 2014, 5 (06) : 2461 - 2465
  • [28] Recent advances of spin crossover research
    Gütlich, P
    van Koningsbruggen, PJ
    Renz, F
    OPTICAL SPECTRA AND CHEMICAL BONDING IN TRANSITION METAL COMPLEXES, 2004, 107 : 27 - 75
  • [29] Bimetallic Iron(3+) Spin-Crossover Complexes Containing a 2,2′-Bithienyl Bridging bis-QsaIH Ligand
    Djukic, Brandon
    Poddutoori, Prashanth K.
    Dube, Paul A.
    Seda, Takele
    Jenkins, Hilary A.
    Lemaire, Martin T.
    INORGANIC CHEMISTRY, 2009, 48 (13) : 6109 - 6116
  • [30] Spin-crossover in complexes of iron(II) carboranes with tris(pyrazol-1-yl)methane
    Shakirova, O. G.
    Daletskii, V. A.
    Lavrenova, L. G.
    Varnek, V. A.
    Rudakov, D. A.
    Potkin, V. I.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (01) : 45 - 52
12345