MoO3 nanorods/Fe2(MoO4)3 nanoparticles composite anode for solid oxide fuel cells

被引:20
作者
Yang, Wei [1 ]
Zhu, Chunling [2 ]
Ma, Zhaohui [1 ]
Sun, Chunwen [1 ]
Chen, Liquan [1 ]
Chen, Yujin [2 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing Key Lab New Energy Mat & Devices,Key Lab, Beijing 100190, Peoples R China
[2] Harbin Engn Univ, Coll Sci, Harbin 150001, Heilongjiang, Peoples R China
基金
美国国家科学基金会;
关键词
Solid oxide fuel cells; Composite anode; Fe-2(MoO4)(3) nanoparticles; MoO3; nanorods; CATHODES; SULFUR;
D O I
10.1016/j.ijhydene.2014.02.102
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MoO3 nanorods/Fe-2(MoO4)(3) nanoparticles composite has been prepared by a hydrothermal method combined with an in situ diffusion growth process. Single cells based on 300 mu m LSGM electrolyte have been fabricated with the MoO3 nanorods/Fe-2(MoO4)(3) nanoparticles composite anode and a composite cathode consisting of Sr0.9Ce0.1CoO3-delta and Sm-doped ceria (SDC). The peak power densities reach 225, 50, 75 mW cm(-2) at 900 degrees C in H-2, CH4 and C3H8, respectively. The cell shows excellent long-term stability at 850 degrees C. The preliminary results demonstrate that the MoO3 nanorods/Fe-2(MoO4)(3) nanoparticles composite is a promising alternative anode for solid oxide fuel cells. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:14411 / 14415
页数:5
相关论文
共 20 条
[1]   Promises and problems of mesoscale materials chemistry or why meso? [J].
Antonietti, M ;
Ozin, GA .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :28-41
[2]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[3]   High-performance solid-oxide fuel cell cathodes based on cobaltite nanotubes [J].
Bellino, Martin G. ;
Sacanell, Joaquin G. ;
Lamas, Diego G. ;
Leyva, Ana G. ;
Walsoe de Reca, Noemi E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (11) :3066-+
[4]   In situ diffusion growth of Fe2(MoO4)3 nanocrystals on the surface of α-MoO3 nanorods with significantly enhanced ethanol sensing properties [J].
Chen, Yujin ;
Meng, Fanna ;
Ma, Chao ;
Yang, Zhiwei ;
Zhu, Chunling ;
Ouyang, Qiuyun ;
Gao, Peng ;
Li, Jianqi ;
Sun, Chunwen .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (25) :12900-12906
[5]  
Chueh WC, 2012, NAT MATER, V11, P155, DOI [10.1038/NMAT3184, 10.1038/nmat3184]
[6]   The preparation of copper-chromium oxide catalysts for hydrogenation [J].
Connor, R ;
Folkers, K ;
Adkins, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1931, 53 (02) :2012-2012
[7]   Molybdate Based Ceramic Negative-electrode Materials for Solid Oxide Cells [J].
Graves, Christopher ;
Sudireddy, Bhaskar Reddy ;
Mogensen, Mogens .
IONIC AND MIXED CONDUCTING CERAMICS 7, 2010, 28 (11) :173-192
[8]   Effect of varying the cation ratio within iron molybdate catalysts for the selective oxidation of methanol [J].
House, Matthew P. ;
Carley, Albert F. ;
Echeverria-Valda, Ricardo ;
Bowker, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (11) :4333-4341
[9]   Direct hydrocarbon solid oxide fuel cells [J].
McIntosh, S ;
Gorte, RJ .
CHEMICAL REVIEWS, 2004, 104 (10) :4845-4865
[10]   Doped CeO2-LaFeO3 Composite Oxide as an Active Anode for Direct Hydrocarbon-Type Solid Oxide Fuel Cells [J].
Shin, Tae Ho ;
Ida, Shintaro ;
Ishihara, Tatsumi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (48) :19399-19407