Chiral Hypervalent, Pentacoordinated Phosphoranes

被引：19

作者：

Krasowska, Dorota ^{[1
]}

Chrzanowski, Jacek ^{[1
]}

Kielbasinski, Piotr ^{[1
]}

Drabowicz, Jozef ^{[1
,2
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Sienkiewicza 112, PL-90363 Lodz, Poland

[2] Jan Dlugosz Univ Czestochowa, Dept Chem Environm Protect & Biotechnol, Armii Krajowej Ave 13-15, PL-42200 Czestochowa, Poland

来源：

MOLECULES | 2016年 / 21卷 / 11期

关键词：

hypervalency; chirality; phosphoranes; Berry pseudorotation; turnstile rotation; RAY CRYSTALLOGRAPHIC ANALYSIS; P-H BOND; BERRY PSEUDOROTATION; BIDENTATE LIGAND; ASYMMETRIC-SYNTHESIS; CIRCULAR-DICHROISM; SPIROPHOSPHORANES; THERMOLYSIS; STEREOCHEMISTRY; CHEMISTRY;

D O I：

10.3390/molecules21111573

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) pentacoordinated, hypervalent mono and bicyclic phosphoranes. The mechanisms of their stereoisomerization and their selected interconversions are also presented.

引用

页数：44

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