Inhibition effect of N-propargyl saccharin as corrosion inhibitor of C38 steel in 1 M HCl, experimental and theoretical study

被引:74
作者
Abdelwedoud, B. Ould [1 ]
Damej, M. [1 ]
Tassaoui, K. [1 ]
Berisha, A. [2 ,3 ]
Tachallait, H. [4 ,5 ]
Bougrin, K. [4 ,5 ]
Mehmeti, V [2 ,3 ]
Benmessaoud, M. [1 ]
机构
[1] Mohammed V Univ Rabat, Higher Sch Technol Sale, Energy Mat & Sustainable Dev Team, Rabat 8007, Morocco
[2] Univ Prishtina, Fac Nat & Math Sci, Dept Chem, Prishtina 10000, Kosovo
[3] Nano Alb Unit Albanian Nanosci & Nanotechnol, Mat Sci Nanochem Res Grp, Tirana 1000, Albania
[4] Mohammed V Univ Rabat, Fac Sci, Geophys Nat Patrimony & Green Chem GEOPAC Res Ctr, Lab Plant Chem & Organ & Bioorgan Synth,URAC23, POB 1014, Rabat 10000, Morocco
[5] Mohammed VI Polytech Univ, Chem & Biochem Sci Green Proc Engn CBS GPE, Lot 660, Hay Moulay Rachid, Benguerir, Morocco
关键词
C38; steel; Corrosion inhibition; Hydrochloric acid; EIS; DFT; Molecular dynamic; E24; CARBON-STEEL; MILD-STEEL; DERIVATIVES; EXTRACT; DFT; PERFORMANCE; ADSORPTION; ENERGIES; BEHAVIOR; SOLIDS;
D O I
10.1016/j.molliq.2022.118784
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The corrosion inhibition method is the technique most used to reduce the cost of corrosion in the indus -trial field, especially in the acidic environment, in which the organic inhibitor has been widely used. For this, the corrosion inhibition of C38 steel in molar hydrochloric acid was examined using N-Propargyl Saccharin (NPS) as an inhibitor. Electrochemical and surface analyzes were performed to identify how this compound inhibits the corrosion of C38. The stark results showed that the inhibitors act as mixed types of inhibitors, reducing the anode and cathode current densities. In addition, this inhibitor improves the resistance to charge transfer of C38 steel, increasing the thickness of the protective layer when the concentration of the inhibitor has been increased. The thermodynamic parameters and the theoretical observations (DFT, MC, and MD) confirm the inhibitor's adsorption interaction with the metal surface. (c) 2022 Published by Elsevier B.V.
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页数:13
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共 70 条
  • [21] Highly durable macromolecular epoxy resin as anticorrosive coating material for carbon steel in 3% NaCl: Computational supported experimental studies
    Dagdag, Omar
    Berisha, Avni
    Safi, Zaki
    Dagdag, Said
    Berrani, Majda
    Jodeh, Shehdeh
    Verma, Chandrabhan
    Ebenso, Eno E.
    Wazzan, Nuha
    El Harfi, Ahmed
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2020, 137 (34)
  • [22] DGEBA-polyaminoamide as effective anti-corrosive material for 15CDV6 steel in NaCl medium: Computational and experimental studies
    Dagdag, Omar
    Berisha, Avni
    Safi, Zaki
    Hamed, Othman
    Jodeh, Shehdeh
    Verma, Chandrabhan
    Ebenso, E. E.
    El Harfi, Ahmed
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2020, 137 (08)
  • [23] New epoxy resin as a corrosion inhibitor for the protection of carbon steel C38 in 1M HCl. experimental and theoretical studies (DFT, MC, and MD)
    Damej, M.
    Hsissou, R.
    Berisha, Avni
    Azgaou, K.
    Sadiku, M.
    Benmessaoud, M.
    Labjar, N.
    El hajjaji, S.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2022, 1254
  • [24] The corrosion inhibition and adsorption behavior of mercaptobenzimidazole and bis-mercaptobenzimidazole on carbon steel in 1.0 M HCl: Experimental and computational insights
    Damej, M.
    Kaya, S.
    EL Ibrahimi, B.
    Lee, H-S.
    Molhi, A.
    Serdaroglu, G.
    Benmessaoud, M.
    Ali, I. H.
    El Hajjaji, S.
    Lgaz, H.
    [J]. SURFACES AND INTERFACES, 2021, 24
  • [25] Experimental and theoretical explorations of S-alkylated mercaptobenzimidazole derivatives for use as corrosion inhibitors for carbon steel in HCl
    Damej, M.
    Benmessaoud, M.
    Zehra, S.
    Kaya, S.
    Lgaz, Hassane
    Molhi, A.
    Labjar, N.
    El Hajjaji, S.
    Alrashdi, Awad A.
    Lee, Han-Seung
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2021, 331 (331)
  • [26] Corrosion inhibition of brass in 3% NaCl solution by 3-methyl-1,2,4-triazol-5-thione
    Damej, M.
    Chebabe, D.
    Benmessaoud, M.
    Dermaj, A.
    Erramli, H.
    Hajjaji, N.
    Srhiri, A.
    [J]. CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, 2015, 50 (02) : 103 - 107
  • [27] Damej M., 2016, J. Mater. Environ. Sci., V7, P738
  • [28] Experimental and Theoretical Study to Understand the Adsorption Process of p-Anisidine and 4-Nitroaniline for the Dissolution of C38 Carbon Steel in 1M HCl
    Damej, Mohamed
    Molhi, Abdu
    Tassaoui, Kawtar
    El Ibrahimi, Brahim
    Akounach, Zahra
    Addi, Abdelaziz Ait
    El Hajjaji, Souad
    Benmessaoud, Mohammed
    [J]. CHEMISTRYSELECT, 2022, 7 (02):
  • [30] From molecules to solids with the DMol3 approach
    Delley, B
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (18) : 7756 - 7764