Inhibition effect of N-propargyl saccharin as corrosion inhibitor of C38 steel in 1 M HCl, experimental and theoretical study

被引:74
作者
Abdelwedoud, B. Ould [1 ]
Damej, M. [1 ]
Tassaoui, K. [1 ]
Berisha, A. [2 ,3 ]
Tachallait, H. [4 ,5 ]
Bougrin, K. [4 ,5 ]
Mehmeti, V [2 ,3 ]
Benmessaoud, M. [1 ]
机构
[1] Mohammed V Univ Rabat, Higher Sch Technol Sale, Energy Mat & Sustainable Dev Team, Rabat 8007, Morocco
[2] Univ Prishtina, Fac Nat & Math Sci, Dept Chem, Prishtina 10000, Kosovo
[3] Nano Alb Unit Albanian Nanosci & Nanotechnol, Mat Sci Nanochem Res Grp, Tirana 1000, Albania
[4] Mohammed V Univ Rabat, Fac Sci, Geophys Nat Patrimony & Green Chem GEOPAC Res Ctr, Lab Plant Chem & Organ & Bioorgan Synth,URAC23, POB 1014, Rabat 10000, Morocco
[5] Mohammed VI Polytech Univ, Chem & Biochem Sci Green Proc Engn CBS GPE, Lot 660, Hay Moulay Rachid, Benguerir, Morocco
关键词
C38; steel; Corrosion inhibition; Hydrochloric acid; EIS; DFT; Molecular dynamic; E24; CARBON-STEEL; MILD-STEEL; DERIVATIVES; EXTRACT; DFT; PERFORMANCE; ADSORPTION; ENERGIES; BEHAVIOR; SOLIDS;
D O I
10.1016/j.molliq.2022.118784
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The corrosion inhibition method is the technique most used to reduce the cost of corrosion in the indus -trial field, especially in the acidic environment, in which the organic inhibitor has been widely used. For this, the corrosion inhibition of C38 steel in molar hydrochloric acid was examined using N-Propargyl Saccharin (NPS) as an inhibitor. Electrochemical and surface analyzes were performed to identify how this compound inhibits the corrosion of C38. The stark results showed that the inhibitors act as mixed types of inhibitors, reducing the anode and cathode current densities. In addition, this inhibitor improves the resistance to charge transfer of C38 steel, increasing the thickness of the protective layer when the concentration of the inhibitor has been increased. The thermodynamic parameters and the theoretical observations (DFT, MC, and MD) confirm the inhibitor's adsorption interaction with the metal surface. (c) 2022 Published by Elsevier B.V.
引用
收藏
页数:13
相关论文
共 70 条
  • [1] Galactomannan as a new bio-sourced corrosion inhibitor for iron in acidic media
    Abbout, Said
    Zouarhi, Meryem
    Chebabe, Driss
    Damej, Mohamed
    Berisha, Avni
    Hajjaji, Najat
    [J]. HELIYON, 2020, 6 (03)
  • [2] Experimental and DFT evaluation of adsorption and inhibitive properties of Moringa oliefera extract on mild steel corrosion in acidic media
    Akalezi, Christogonus Oudney
    Maduabuchi, Arinze Chidiebere
    Enenebeaku, Conrad Kenechukwu
    Oguzie, Emeka Emmanuel
    [J]. ARABIAN JOURNAL OF CHEMISTRY, 2020, 13 (12) : 9270 - 9282
  • [3] A theoretical and experimental study of the adsorptive removal of hexavalent chromium ions using graphene oxide as an adsorbent
    Alija, Ardhmeri
    Gashi, Drinisa
    Plakaj, Rilinda
    Omaj, Admir
    Thaci, Veprim
    Reka, Arianit
    Avdiaj, Sefer
    Berisha, Avni
    [J]. OPEN CHEMISTRY, 2020, 18 (01): : 936 - 942
  • [4] Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution
    Aljourani, J.
    Raeissi, K.
    Golozar, M. A.
    [J]. CORROSION SCIENCE, 2009, 51 (08) : 1836 - 1843
  • [5] Geometry optimization of solids using delocalized internal coordinates
    Andzelm, J
    King-Smith, RD
    Fitzgerald, G
    [J]. CHEMICAL PHYSICS LETTERS, 2001, 335 (3-4) : 321 - 326
  • [6] [Anonymous], QUANTUM CHEM EXPT EV
  • [7] Aoufir E., 2017, MOROCCAN J CHEM TRIA
  • [8] Imidazolium-derived polymeric ionic liquid as a green inhibitor for corrosion inhibition of mild steel in 1.0 M HCl: Experimental and computational study
    Ardakani, Ebrahim Kamali
    Kowsari, Elaheh
    Ehsani, Ali
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2020, 586
  • [9] Ionic liquids derived from α-amino acid ester salts as potent green corrosion inhibitors for mild steel in 1M HCl
    Aslam, Ruby
    Mobin, Mohammad
    Huda
    Obot, Ime B.
    Alamri, Aeshah H.
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2020, 318 (318)