Hierarchical porous carbon with ordered straight micro-channels templated by continuous filament glass fiber arrays for high performance supercapacitors

被引:66
作者
Jia, Dedong [1 ]
Yu, Xin [1 ]
Tan, Hua [2 ]
Li, Xuequan [2 ]
Han, Feng [3 ]
Li, Linlin [1 ]
Liu, Hong [1 ,2 ]
机构
[1] Chinese Acad Sci, Natl Ctr Nanosci & Technol NCNST, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[3] German Aerosp Ctr, Inst Engn Thermodynam, D-70569 Stuttgart, Germany
关键词
ACTIVATED CARBONS; SURFACE-AREA; NANOSTRUCTURED MATERIALS; MESOPOROUS CARBONS; MATERIALS SCIENCE; PORE STRUCTURE; LAYER; ELECTRODES; GRAPHENE; NANOSPHERES;
D O I
10.1039/c6ta09229b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hierarchical porous carbon with highly ordered straight micro-channels was prepared though a facile melt vacuum infiltration method using continuous filament glass fiber arrays as the template and glucose as the precursor. The as-prepared carbon material shows high specific surface areas up to 1880 m(2) g(-1) profited from the unique structure of straight micro-channels. A fine pore structure is formed in the channel wall through KOH activation after the removal of the glass fiber array. Electrochemical evaluation of the carbon material indicates that the hierarchical porous carbon exhibits a high specific capacitance of 283 F g(-1) at a current density of 0.25 A g(-1) with an alkaline electrolyte (6 M KOH) in a threeelectrode system. It also demonstrates excellent cycling stability with a capacity retention of 88.5% over 10 000 cycles at a high current density of 6 A g(-1). These exciting results demonstrate a very simple and low-cost method for large-scale preparation of electrode materials for supercapacitors.
引用
收藏
页码:1516 / 1525
页数:10
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