Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework

被引：8

作者：

Agou, Tomohiro ^{[1
]}

Wada, Nao ^{[1
]}

Fujisawa, Kiyoshi ^{[2
]}

Hosoya, Takaaki ^{[1
]}

Mizuhata, Yoshiyuki ^{[3
]}

Tokitoh, Norihiro ^{[3
]}

Fukumoto, Hiroki ^{[1
]}

Kubota, Toshio ^{[1
]}

机构：

[1] Ibaraki Univ, Grad Sch Sci & Engn, Dept Quantum Beam Sci, 4-12-1 Nakanarusawa, Hitachi, Ibaraki 3168511, Japan

[2] Ibaraki Univ, Fac Sci, Dept Chem, Mito, Ibaraki 3108512, Japan

[3] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 15期

关键词：

CATALYZED ASYMMETRIC 1,4-ADDITION; COPPER(I) HALIDE-COMPLEXES; IRON CARBONYL-COMPLEXES; SILVER(I) COMPLEXES; PHOTOPHYSICAL PROPERTIES; DIPHOSPHINE LIGANDS; CRYSTAL; CHEMISTRY; LUMINESCENCE; DERIVATIVES;

D O I：

10.1021/acs.inorgchem.8b01111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.

引用

页码：9105 / 9114

页数：10

共 83 条

[51] Synthesis and structural characterization of binuclear silver(I) complexes bridged by three polydentate phosphine ligands [J].