Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework

被引：7
作者：
Agou, Tomohiro [1 ]
Wada, Nao [1 ]
Fujisawa, Kiyoshi [2 ]
Hosoya, Takaaki [1 ]
Mizuhata, Yoshiyuki [3 ]
Tokitoh, Norihiro [3 ]
Fukumoto, Hiroki [1 ]
Kubota, Toshio [1 ]
机构：
[1] Ibaraki Univ, Grad Sch Sci & Engn, Dept Quantum Beam Sci, 4-12-1 Nakanarusawa, Hitachi, Ibaraki 3168511, Japan
[2] Ibaraki Univ, Fac Sci, Dept Chem, Mito, Ibaraki 3108512, Japan
[3] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 15期
关键词：
CATALYZED ASYMMETRIC 1,4-ADDITION; COPPER(I) HALIDE-COMPLEXES; IRON CARBONYL-COMPLEXES; SILVER(I) COMPLEXES; PHOTOPHYSICAL PROPERTIES; DIPHOSPHINE LIGANDS; CRYSTAL; CHEMISTRY; LUMINESCENCE; DERIVATIVES;
D O I：
10.1021/acs.inorgchem.8b01111
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cu(I), Ag(I), and Au(I) complexes of monophosphine or bisphosphine ligands based on the 3,3,4,4,5,5-hexafluorocyclopentene skeleton were synthesized and structurally characterized by X-ray crystallographic analysis. The electron-withdrawing nature of these polyfluorinated phosphines was experimentally revealed via UV/vis absorption studies and crystal structure analysis. Successful catalytic application of the Au(I) complex for alkyne hydration reactions was investigated.
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收藏
页码：9105 / 9114
页数：10
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