Tuning the wettability of highly transparent Nb2O5 nano-sliced coatings to enhance anti-corrosion property

被引:18
作者
Kumar, Ashwani [1 ]
Malik, Gaurav [1 ]
Adalati, Ravikant [1 ]
Chawla, Vipin [1 ]
Pandey, Mritunjay Kumar [2 ]
Chandra, Ramesh [1 ]
机构
[1] Indian Inst Technol Roorkee, Inst Instrumentat Ctr IIC, Nanosci Lab, Roorkee 247667, Uttar Pradesh, India
[2] DRDO HQ, Directorate Extramural Res & Intellectual Propert, New Delhi 110011, India
关键词
Nb2O5; films; Sputtering; Deposition temperature; Corrosion; Optical properties; THIN-FILMS; OPTICAL-PROPERTIES; CORROSION PROPERTIES; SURFACE-MORPHOLOGY; TEMPERATURE; ALLOY; ANGLE;
D O I
10.1016/j.mssp.2020.105513
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In the present work, the deposition temperature-dependent optical, wetting and corrosion properties of niobium oxide (Nb2O5) coatings was investigated. The Nb2O5 thin films were deposited on two different substrates i.e. glass and stainless steel (SS 304) by using sputtering technique at various deposition temperatures (RT, 100 & 200 degrees C) in Ar:O-2 (3:1) atmosphere. To confirm the pertinent growth of the prepared samples, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) were employed. The optical, wetting and corrosion studies of the synthesized samples were executed using UV Vis-spectroscopy (UV), contact angle (CA) and cyclic voltammetry (CV), respectively. The aquatic corrosion studies of Nb2O5 films deposited on SS samples were estimated under two dissimilar ways. The Tafel plot (polarization curve) and EIS (electrochemical impedance spectra) were accomplished in terms of polarization resistance (R-p) under saline water (3.5% NaCl aqueous solution) environment. Nano-sliced Nb2O5 film deposited at 200 degrees C on SS substrate exhibited excellent optical, good transparency, wetting and material protective behavior i.e. transmittance (similar to 91%), refractive index (n) similar to 2.3045, hydrophobicity (theta(w)) similar to 97.3 degrees, corrosion rate similar to 6.9 x 10(-3) mm/y and R-p similar to 2.78 x 10(6) Omega-cm(2) in comparison to the other samples (coated and uncoated).
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页数:11
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