1D Coordination Polymer Based on the [Mo36O114(H2O)14]12- Building Block with [Cu(H2O)2]2+ Linker Exhibiting Electrocatalytic Activities for H2O2 Reduction

被引：2

作者：

Gao, Qiao ^{[1
]}

Xu, Lin ^{[2
]}

Gong, Ji-Yu ^{[1
]}

Wang, Wei-Nan ^{[1
]}

机构：

[1] Changchun Univ Chinese Med, Sch Pharmaceut Sci, Changchun 130117, Jilin, Peoples R China

[2] Northeast Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2019年 / 30卷 / 04期

关键词：

Polyoxometalates; One-dimensional; Coordination polymer; Electrochemistry; POLYOXOMETALATE; NANOSCALE; MOIETIES; CHAIN; SOLAR; UNITS;

D O I：

10.1007/s10876-019-01565-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 1D coordination polymer [NH4](4)[Hmorph](6)[Cu(H2O)(2)][Mo36O114(H2O)(14)]28H(2)O (1) has been isolated by utilizing a one-pot self-assembly method and structurally characterized. Compound 1 exhibits the first example of 1D chain framework constructed from the [Mo36O114(H2O)(14)](12-) fragments linked alternately with [Cu(H2O)(2)](2+) units. Electrochemical experiments reveal that 1-CPE exhibits the multi-electron redox processes ascribed to Mo-VI centers, and shows good electrocatalytic activity for H2O2 reduction. The photophysical investigations indicate that compound 1 bears the band gap value at ca. 2.92eV, which is similar to inorganic semiconductor materials.

引用

页码：1065 / 1069

页数：5

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