1D Coordination Polymer Based on the [Mo36O114(H2O)14]12- Building Block with [Cu(H2O)2]2+ Linker Exhibiting Electrocatalytic Activities for H2O2 Reduction

被引：2

作者：

Gao, Qiao ^{[1
]}

Xu, Lin ^{[2
]}

Gong, Ji-Yu ^{[1
]}

Wang, Wei-Nan ^{[1
]}

机构：

[1] Changchun Univ Chinese Med, Sch Pharmaceut Sci, Changchun 130117, Jilin, Peoples R China

[2] Northeast Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2019年 / 30卷 / 04期

关键词：

Polyoxometalates; One-dimensional; Coordination polymer; Electrochemistry; POLYOXOMETALATE; NANOSCALE; MOIETIES; CHAIN; SOLAR; UNITS;

D O I：

10.1007/s10876-019-01565-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 1D coordination polymer [NH4](4)[Hmorph](6)[Cu(H2O)(2)][Mo36O114(H2O)(14)]28H(2)O (1) has been isolated by utilizing a one-pot self-assembly method and structurally characterized. Compound 1 exhibits the first example of 1D chain framework constructed from the [Mo36O114(H2O)(14)](12-) fragments linked alternately with [Cu(H2O)(2)](2+) units. Electrochemical experiments reveal that 1-CPE exhibits the multi-electron redox processes ascribed to Mo-VI centers, and shows good electrocatalytic activity for H2O2 reduction. The photophysical investigations indicate that compound 1 bears the band gap value at ca. 2.92eV, which is similar to inorganic semiconductor materials.

引用

页码：1065 / 1069

页数：5

共 33 条

[1] [Anonymous], 2010, CRYSALISCCD CRYSALIS
[2] Structural insights into two inorganic-organic hybrids based on chiral amino acids and polyoxomolybdates
Arefian, Mina
Mirzaei, Masoud
Eshtiagh-Hosseini, Hossein
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2018, 1156 : 550 - 558
[3] From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications
Cronin, Leroy
Mueller, Achim
[J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) : 7333 - 7334
[4] Polyoxometalate-based materials for efficient solar and visible light harvesting: application to the photocatalytic degradation of azo dyes
Dolbecq, Anne
Mialane, Pierre
Keita, Bineta
Nadjo, Louis
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (47) : 24509 - 24521
[5] Sandwich-type copper(II) cluster complex based on novel inorganic ligand [AsIIIMo10VIV4VO47]11-with semiconductor-like property and electrochemical sensing of ascorbic acid and nitrite
Gao, Qiao
Hu, Dong-Hua
Li, De-Hui
Duan, Ming-Hua
Wu, Yong
[J]. INORGANICA CHIMICA ACTA, 2019, 487 : 107 - 111
[6] Multidimensional all-inorganic frameworks based on new molybdovanadate cluster of [VMo7O28]9- with Cu(II) linker showing semiconducting behavior
Gao, Qiao
Li, Fengyan
Sun, Minghui
Xu, Lin
Wang, Yuchao
Bai, Jie
[J]. CRYSTENGCOMM, 2014, 16 (33): : 7681 - 7688
[7] A series of organic-inorganic hybrid materials consisting of flexible organic amine modified polyoxomolybdates: synthesis, structures and properties
Gong, Chunhua
Zeng, Xianghua
Zhu, Chengfeng
Shu, Jiahui
Xiao, Pingxiu
Xu, Hao
Liu, Lichun
Zhang, Junyong
Zeng, Qingdao
Xie, Jingli
[J]. RSC ADVANCES, 2016, 6 (108): : 106248 - 106259
[8] Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations
Izarova, N. V.
Sokolov, M. N.
Samsonenko, D. G.
Rothenberger, A.
Fenske, D.
Fedin, V. P.
[J]. RUSSIAN CHEMICAL BULLETIN, 2008, 57 (01) : 78 - 82
[9] One-, two-, and three-dimensional coordination polymers built from large Mo36-polyoxometalate anionic units and lanthanide cations
Izarova, NV
Sokolov, MN
Samsonenko, DG
Rothenberger, A
Naumov, DY
Fenske, D
Fedin, VP
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (24) : 4985 - 4996
[10] Loading Co3N nanoparticles as efficient cocatalysts over Zn0.5Cd0.5S for enhanced H2 evolution under visible light
Jin, Zhanbin
Wei, Tingting
Li, Lixue
Li, Fengyan
Tao, Ran
Xu, Lin
[J]. DALTON TRANSACTIONS, 2019, 48 (08) : 2676 - 2682

← 1 2 3 4 →