Direct C-H Metalation with Chromium(II) and Iron(II): Transition-Metal Host/Benzenediide Guest Magnetic Inverse-Crown Complexes

被引：49

作者：

Albores, Pablo ^{[3
]}

Carrella, Luca M. ^{[3
]}

Clegg, William ^{[2
]}

Garcia-Alvarez, Pablo ^{[1
]}

Kennedy, Alan R. ^{[1
]}

Klett, Jan ^{[1
]}

Mulvey, Robert E. ^{[1
]}

Rentschler, Eva ^{[3
]}

Russo, Luca ^{[2
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Newcastle, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

alkali metals; chromium; inverse crown compounds; iron; metalation; MEDIATED MANGANATION; CRYSTAL-STRUCTURES; REACTIVITY; STABILITY; STATE;

D O I：

10.1002/anie.200805566

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Check M(etal)ate: The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (usually the weaker piece) to make a direct deadly hit on the king (benzene) in this game of elemental chess. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3317 / 3321

页数：5

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