Effect of ZnO Seed Layer and TiO2 Coating Treatments on Aligned TiO2/ZnO Nanostructures for Dye-Sensitized Solar Cells

被引:3
作者
Chen, Lung-Chuan [1 ]
Chen, Jean-Hong [1 ]
Tsai, Shuei-Feng [1 ]
Wang, Guan-Wen [1 ]
机构
[1] Kun Shan Univ, Dept Mat Engn, Tainan 710, Taiwan
来源
APPLIED SCIENCE AND PRECISION ENGINEERING INNOVATION, PTS 1 AND 2 | 2014年 / 479-480卷
关键词
ZnO; TiO; seed; etching; dye sensitizedn solar cells; PHOTOCATALYTIC ACTIVITY; THIN-FILMS; NANORODS; NANOPARTICLES; TEMPERATURE; PERFORMANCE; DEPOSITION; EFFICIENCY; ARRAYS;
D O I
10.4028/www.scientific.net/AMM.479-480.69
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
A chemical bath deposition (CBD) method was applied to grow zinc oxide nanorod arrays on transparent conductive oxides acting as templates for the synthesis of TiO2/ZnO nanostructures (TiO2/ZNR) followed by HCl etching, and then these nanostructures were assembled as anodes in dye-sensitized solar cells. The ZnO nanorods, predominantly grew with good crystallinity along c-axis, exhibit wurtzite structure with smooth surface. Etching of the TiO2/ZNR by HCl changes the most preferential crystal plane of ZnO from (002) to (100) and significantly increases the atomic ratio of Ti/Zn. Optical absorption measurements indicate a band gap energy of 3.1 eV for ZNR and TiO2/ZNR. Increasing the spin coating time (SCT) of TiO2 on ZNR increases the PL intensity. The seed layer number (SLN) of ZnO exerts moderate influence on the photo-to-electricity conversion and an optimum SLN was observed for this study.
引用
收藏
页码:69 / 74
页数:6
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