Capacity fade in high energy silicon-graphite electrodes for lithium-ion batteries

被引：43

作者：

Dose, W. M. ^{[1
]}

Piernas-Munoz, M. J. ^{[1
]}

Maroni, V. A. ^{[1
]}

Trask, S. E. ^{[1
]}

Bloom, I ^{[1
]}

Johnson, C. S. ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 29期

关键词：

FAILURE MECHANISMS; ANODE MATERIALS; LI; CELLS;

D O I：

10.1039/c8cc00456k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A silicon-graphite blended anode is paired with a high capacity LiFePO4 reference/counter electrode to track irreversibility and lithium inventory. The LiFePO4 electrode provides a reliable, flat potential for dQ dV 1 analysis of LixSi and LixC electrochemical reactions. We relate this electrochemistry to the morphological and physical changes taking place.

引用

页码：3586 / 3589

页数：4

共 23 条

[1] A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions [J].

Aurbach, D ;

Zinigrad, E ;

Cohen, Y ;

Teller, H .

SOLID STATE IONICS, 2002, 148 (3-4) :405-416

[2] Colossal reversible volume changes in lithium alloys [J].

Beaulieu, LY ;

Eberman, KW ;

Turner, RL ;

Krause, LJ ;

Dahn, JR .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (09) :A137-A140

[3] Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? [J].

Besenhard, JO ;

Yang, J ;

Winter, M .

JOURNAL OF POWER SOURCES, 1997, 68 (01) :87-90

[4] One-to-One Comparison of Graphite-Blended Negative Electrodes Using Silicon Nanolayer-Embedded Graphite versus Commercial Benchmarking Materials for High-Energy Lithium-Ion Batteries [J].

Chae, Sujong ;

Kim, Namhyung ;

Ma, Jiyoung ;

Cho, Jaephil ;

Ko, Minseong .

ADVANCED ENERGY MATERIALS, 2017, 7 (15)

[5] RETRACTED: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries (Retracted Article) [J].

Dash, Ranjan ;

Pannala, Sreekanth .

SCIENTIFIC REPORTS, 2016, 6

[6] Nano-network electronic conduction in iron and nickel olivine phosphates [J].

Herle, PS ;

Ellis, B ;

Coombs, N ;

Nazar, LF .

NATURE MATERIALS, 2004, 3 (03) :147-152

[7] Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells [J].

Kasavajjula, Uday ;

Wang, Chunsheng ;

Appleby, A. John .

JOURNAL OF POWER SOURCES, 2007, 163 (02) :1003-1039

[8] Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms [J].

Key, Baris ;

Morcrette, Mathieu ;

Tarascon, Jean-Marie ;

Grey, Clare P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (03) :503-512

[9] Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows [J].

Klett, Matilda ;

Gilbert, James A. ;

Pupek, Krzysztof Z. ;

Trask, Stephen E. ;

Abraham, Daniel P. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (01) :A6095-A6102

[10] Reliable reference electrodes for lithium-ion batteries [J].

La Mantia, F. ;

Wessells, C. D. ;

Deshazer, H. D. ;

Cui, Yi .

ELECTROCHEMISTRY COMMUNICATIONS, 2013, 31 :141-144

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