Thermochemical and Energy Characteristics of Dimers of Terfurazanoazepines

被引：3

作者：

Lempert, D. B. ^{[1
]}

Kazakov, A., I ^{[1
]}

Nabatova, A., V ^{[1
]}

Dashko, D., V ^{[2
]}

Stepanov, A., I ^{[2
]}

Shilov, G., V ^{[1
]}

Aldoshin, S. M. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia

[2] Tekhnol Special Design & Technol Bur, St Petersburg 193076, Russia

[3] Lomonosov Moscow State Univ, Moscow 119991, Russia

来源：

COMBUSTION EXPLOSION AND SHOCK WAVES | 2020年 / 56卷 / 06期

关键词：

7,7 '-bis(terfurazan[3,4-b:3,4 '-d:3 '',4 ''-f]azepine (I); 1,1 '-dioxide-7,7 '-bis(terfurazan[3,4,b:3,4 '-d:3 '',4 ''-f]azepine (II); azepine; enthalpy of combustion; enthalpy of formation; crystal structure; solid composite propellant (SCP); specific impulse;

D O I：

10.1134/S0010508220060015

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The heat of combustion and the enthalpy of formation of 7,7 '-bis(terfurazan[3,4-b:3,4 '-d:3 '',4 ''-f]azepine (I) and 1,1 '-dioxide-7,7 '-bis(terfurazan[3,4-b:3,4 '-d:3 '',4 ''-f] azepine (II), were experimentally determined. Product I was studied by X-ray diffraction analysis, and its crystallographic characteristics were determined. The efficiency of using compounds I and II as components of solid composite propellants was analyzed, and the type of compositions in which they are more effective than HMX was determined.

引用

页码：621 / 628

页数：8

共 15 条

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