catena-poly[[diaqua(1,10-phenanthroline-κ2N,N′)-cobalt(II)]-μ-acetylenedicarboxylato-κ2O:O′]

被引：12

作者：

Wang, Huan-Yu ^{[1
]}

Gao, Shan ^{[1
]}

Huo, Li-Hua ^{[1
]}

Zhao, Jing-Gui ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Lab Funct Mat, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806044734

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Co(C4O4)(C12H8N2)(H2O)(2)](n), the Co-II atom exhibits a slightly distorted octahedral coordination geometry involving two N atoms from 1,10-phenanthroline, two O atoms from two acetylenedicarboxylate (ace(2-)) dianions and two water O atoms. The ace(2-) ligand acts in a bis-monodentate mode to connect two adjacent Co-II atoms, forming chains along the b axis. A three-dimensional supramolecular architecture is constructed via O-H center dot center dot center dot O hydrogen bonds and pi-pi interactions.

引用

页码：M3152 / M3154

页数：3

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