Asymmetric Michael reactions using tartrate-based magnesium catalysts

被引：0

作者：

MacCulloch, AC

Yolka, S

Jackson, RFW

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

SYNLETT | 2002年 / 10期

关键词：

asymmetric catalysis; asymmetric synthesis; Michael additions; magnesium; nucleophilic additions;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalysts derived from a combination of dialkyl tartrates and dibutylmagnesium are effective for the asymmetric Michael addition of dibenzyl malonate to enones with ee's up to 58%.

引用

页码：1700 / 1702

页数：3

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