Determination of sodium diethyldithiocarbamate in water by anodic voltammetry using a boron-doped diamond electrode

被引：17
|
作者：
Radovan, Ciprian
Manea, Florica
机构：
[1] W Univ Timisoara, Lab Electrochem, Timisoara 300115, Romania
[2] Politehn Univ Timisoara, Timisoara 300006, Romania
来源：
ELECTROANALYSIS | 2007年 / 19卷 / 01期
关键词：
sodium diethyldithiocarbamate; cyclic voltammetry; chronoamperometry; anodic oxidation; boron-doped diamond electrode;
D O I：
10.1002/elan.200603710
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An electrochemical study was made of the anodic behavior of sodium diethyldithiocarbamate (DEDTC) using a boron-doped diamond electrode (BDDE) in sodium sulfate supporting electrolyte. This paper presents a new alternative for the electroanalytical determination of DEDTC in protic media, using cyclic voltammetry or chronoamperometry. Linear plots of current vs. concentration correlated with anodic stepwise oxidation were obtained in delimited potential ranges with very good correlation coefficients.
引用
收藏
页码：91 / 95
页数：5
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