Photocatalytic Carbon-Nanotube-TiO2 Composites

被引:1285
作者
Woan, Karran [1 ]
Pyrgiotakis, Georgios [1 ]
Sigmund, Wolfgang [1 ]
机构
[1] Univ Florida, Dept Mat Sci & Engn, Gainesville, FL 32611 USA
关键词
WALLED CARBON NANOTUBES; MIXED-PHASE TIO2; SOL-GEL METHOD; TITANIUM-DIOXIDE; NANOCOMPOSITES; PHOTODEGRADATION; MECHANISMS; NANOFIBERS; CATALYSTS; PHENOL;
D O I
10.1002/adma.200802738
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The literature and advances in photocatalysis based on the combination of titania (TiO2) and carbon nanotubes is presented. The semiconductor basis for photocatalysis is introduced for anatase and rutile. Furthermore, the proposed mechanisms of catalytic enhancement resulting from the pairing of the titania semiconductor with either metallic, semiconducting, or defect-rich carbon nanotubes (CNT) is discussed. Differences are apparent for the mixtures and chemically bonded CNT-TiO2 composites. The article then highlights the recent advances in the synthesis techniques for these composites and their photocatalytic reactions with organic, inorganic, and biological agents. Finally, various applications and challenges for these composite materials are reported.
引用
收藏
页码:2233 / 2239
页数:7
相关论文
共 47 条
  • [1] Carbon nanotubes synergistically enhance photocatalytic activity of TiO2
    Ahmmad, Bashir
    Kusumoto, Yoshihumi
    Somekawa, Shouichi
    Ikeda, Miyuki
    [J]. CATALYSIS COMMUNICATIONS, 2008, 9 (06) : 1410 - 1413
  • [2] Ahmmad B, 2007, J ADV OXID TECHNOL, V10, P415
  • [3] [Anonymous], 2005, MRS ONLINE P LIBR
  • [4] Multi-walled carbon nanotubes/TiO2 composite nanofiber by electrospinning
    Aryal, Santosh
    Kim, Chul Ki
    Kim, Kwan-Woo
    Khil, Myung Seob
    Kim, Hak Yong
    [J]. MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2008, 28 (01): : 75 - 79
  • [5] A STRUCTURAL INVESTIGATION OF TITANIUM-DIOXIDE PHOTOCATALYSTS
    BICKLEY, RI
    GONZALEZCARRENO, T
    LEES, JS
    PALMISANO, L
    TILLEY, RJD
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1991, 92 (01) : 178 - 190
  • [6] Industrial production of multiwalled carbon nanotubes
    Bierdel, M.
    Buchholz, S.
    Michele, V.
    Mleczko, L.
    Rudolf, R.
    Voetz, M.
    Wolf, A.
    [J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2007, 244 (11): : 3939 - 3943
  • [7] Hydrothermal preparation of ZnO:CNT and TiO2:CNT composites and their photocatalytic applications
    Byrappa, K.
    Dayananda, A. S.
    Sajan, C. P.
    Basavalingu, B.
    Shayan, M. B.
    Soga, K.
    Yoshimura, M.
    [J]. JOURNAL OF MATERIALS SCIENCE, 2008, 43 (07) : 2348 - 2355
  • [8] Photoinduced reactivity of titanium dioxide
    Carp, O
    Huisman, CL
    Reller, A
    [J]. PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) : 33 - 177
  • [9] Structure, wettability and photocatalytic activity of CO2 laser sintered TiO2/multi-walled carbon nanotube coatings
    Castro, M. R. S.
    Sam, E. D.
    Veith, M.
    Oliveira, P. W.
    [J]. NANOTECHNOLOGY, 2008, 19 (10)
  • [10] Enhanced magnetic coercivities in Fe nanowires
    Grobert, N
    Hsu, WK
    Zhu, YQ
    Hare, JP
    Kroto, HW
    Walton, DRM
    Terrones, M
    Terrones, H
    Redlich, P
    Rühle, M
    Escudero, R
    Morales, F
    [J]. APPLIED PHYSICS LETTERS, 1999, 75 (21) : 3363 - 3365