Ruthenium complexes of eilatin: Face selectivity in octahedral geometry; Synthesis of [Ru(bpy)(2)(eilatin)](2+) and [Ru(phen)(2)(eilatin)](2+)

被引：27

作者：

Rudi, A ^{[1
]}

Kashman, Y ^{[1
]}

Gut, D ^{[1
]}

Lellouche, F ^{[1
]}

Kol, M ^{[1
]}

机构：

[1] TEL AVIV UNIV,RAYMOND & BEVERLY SACKLER FAC EXACT SCI,SCH CHEM,IL-69978 TEL AVIV,ISRAEL

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606944d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eilatin, a marine alkaloid, is a potentially bifacial ligand that prefers to bind through its less hindered face in sterically demanding geometries as evident by the selective synthesis of two octahedral ruthenium complexes.

引用

页码：17 / 18

页数：2

共 14 条

[1] SYNTHESIS AND STUDY OF A MIXED-LIGAND RUTHENIUM(II) COMPLEX IN ITS GROUND AND EXCITED-STATES - BIS(2,2'-BIPYRIDINE)(DIPYRIDO[3,2-A, 2',3'-C]PHENAZINE-N4N5)RUTHENIUM(II)
AMOUYAL, E
HOMSI, A
CHAMBRON, JC
SAUVAGE, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06): : 1841 - 1845
[2] STEPWISE SYNTHESES OF MONONUCLEAR AND DINUCLEAR RUTHENIUM TPPHZ COMPLEXES [(BPY)(2)RU(TPPHZ)](2-) AND [(BPY)(2)RU(TPPHZ)RU(BPY)(2)](4+)(TPPHZ=TETRAPYRIDO[3,2-A(2',3'-C)-3'',2''-H(2'',3'''-J)]PHENAZINE)
BOLGER, J
GOURDON, A
ISHOW, E
LAUNAY, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (17) : 1799 - 1800
[3] DENDRIMERS OF NANOMETER-SIZE BASED ON METAL-COMPLEXES - LUMINESCENT AND REDOX-ACTIVE POLYNUCLEAR METAL-COMPLEXES CONTAINING UP TO 22 METAL CENTERS
CAMPAGNA, S
DENTI, G
SERRONI, S
JURIS, A
VENTURI, M
RICEVUTO, V
BALZANI, V
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (04) : 211 - 221
[4] THE BIOMIMETIC SYNTHESIS OF MARINE ALKALOID RELATED PYRIDO[2,3,4-KL]ACRIDINES AND PYRROLO[2,3,4-KL]ACRIDINES
GELLERMAN, G
RUDI, A
KASHMAN, Y
[J]. TETRAHEDRON, 1994, 50 (45) : 12959 - 12972
[5] HIGH-SPIN AND LOW-SPIN COMPLEXES WITH SIMILAR LIGANDS .2. IRON(II) COMPLEXES WITH STERICALLY HINDERED ANALOGS OF 2,2'-BIPYRIDYL
HARRIS, CM
WONG, H
SINN, E
PATIL, HRH
KOKOT, S
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1972, 25 (08) : 1631 - &
[6] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE
JURIS, A
BALZANI, V
BARIGELLETTI, F
CAMPAGNA, S
BELSER, P
VONZELEWSKY, A
[J]. COORDINATION CHEMISTRY REVIEWS, 1988, 84 : 85 - 277
[7] RESONANCE RAMAN-SPECTRA AND SPECTROELECTROCHEMICAL PROPERTIES OF MONOMETALLIC AND POLYMETALLIC RUTHENIUM COMPLEXES WITH 1,4,5,8,9,12-HEXAAZATRIPHENYLENE
KIRSCHDEMESMAEKER, A
JACQUET, L
MASSCHELEIN, A
VANHECKE, F
HEREMANS, K
[J]. INORGANIC CHEMISTRY, 1989, 28 (12) : 2465 - 2470
[8] SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF RUTHENIUM AND OSMIUM COMPLEXES WITH STERICALLY HINDERING LIGANDS .2. TRIS COMPLEXES WITH 2-(2'-PYRIDYL)QUINOLINE AND 2,2'-BIQUINOLINE
KLASSEN, DM
[J]. INORGANIC CHEMISTRY, 1976, 15 (12) : 3166 - 3168
[9] INTRAMOLECULAR CONTROL OF EXCITED-STATE ELECTRON AND ENERGY ELECTRON-TRANSFER
MEYER, TJ
[J]. PURE AND APPLIED CHEMISTRY, 1990, 62 (06) : 1003 - 1009
[10] NAKAHARA S, 1993, HETEROCYCLES, V36, P1139

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